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- W3097130595 endingPage "272" @default.
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- W3097130595 abstract "Abstract Functionalization of polycyclic aromatic hydrocarbons (PAHs) with functional groups is essential for tuning the optoelectronic properties, solid stacking and solubility. α‐Iminonitriles are composite functional groups (CFGs) containing imine (C=N−R) and nitrile (CN) moieties with strong electron‐withdrawing character and good stability, which could be readily introduced through several effective synthetic methods. α‐Iminonitriles have been widely used as intermediates for organic transformations but hold untapped potential for modification of organic functional materials. We herein disclose that α‐iminonitriles are eminent groups for modifying the properties of pyrene. The introduction of α‐iminonitriles to pyrene causes many changes: significantly lowering the LUMOs, red‐shift in absorption and emission spectra, tuning the solid‐stacking, triggering aggregation‐induced emission and white‐light emission. This work indicates that CFGs such as α‐iminonitriles may provide extra toolkits for the functionalization of organic functional materials which would help to tap the potentials of novel or existed materials." @default.
- W3097130595 created "2020-11-09" @default.
- W3097130595 creator A5009164181 @default.
- W3097130595 creator A5009796483 @default.
- W3097130595 creator A5016275070 @default.
- W3097130595 creator A5024807312 @default.
- W3097130595 creator A5068596196 @default.
- W3097130595 creator A5085372592 @default.
- W3097130595 date "2020-11-17" @default.
- W3097130595 modified "2023-10-16" @default.
- W3097130595 title "α‐Iminonitriles: Composite Functional Groups for Functionalization of Pyrene" @default.
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