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- W3097334479 abstract "(+)-Crambescin A belongs to the polycyclic guanidine natural product family and has been shown to possess various medically important properties. The chiral bicyclic guanidine structure of (+)-crambescin A presents a challenge for chemical synthesis. Here we implement a novel asymmetric Biginelli reaction strategy to achieve the enantiospecific total synthesis of (+)-crambescin A in only 8 steps from the abundant and inexpensive aliphatic aldehyde, urea and methyl 3-oxobutanoate." @default.
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- W3097334479 date "2020-01-01" @default.
- W3097334479 modified "2023-10-13" @default.
- W3097334479 title "Eight-step total synthesis of (+)-crambescin A" @default.
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- W3097334479 doi "https://doi.org/10.1039/d0ra08726b" @default.
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