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• W3097434530 abstract "In this study, a polymerized twisted nematic (TN) network was used as an extrinsic chiral platform to overcome the heterogeneity during spontaneous symmetry breaking in a mixed system comprising an achiral bent-core molecule and rod-like mesogen. The TN platform was prepared by photopolymerizing a reactive mesogen dispersed in a low molecular weight liquid crystal with TN orientation. The use of TN orientation to correct the degeneracy in bent-core molecular systems has been previously reported; however, to the best of our knowledge, this is the first study that uses an extrinsic chiral platform of a polymerized TN network. The heterogeneity in the nano-segregated phase of the achiral mixture was suppressed using the extrinsic TN platform with a twisted angle θ of ≥ |±30°|. When an achiral mixture doped with a luminescent guest molecule was refilled into the extrinsic chiral platform, preferential deracemization with one-handedness occurred, corresponding to the handedness of the TN platform. Therefore, circularly polarized luminescence with a preferential handedness can be achieved using this extrinsic chiral platform." @default.
• W3097434530 created "2020-11-09" @default.
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• W3097434530 date "2020-10-29" @default.
• W3097434530 modified "2023-10-17" @default.
• W3097434530 title "Preferential Circularly Polarized Luminescence from a Nano-Segregated Liquid Crystalline Phase Using a Polymerized Twisted Nematic Platform" @default.
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• W3097434530 doi "https://doi.org/10.3390/polym12112529" @default.
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