Matches in SemOpenAlex for { <https://semopenalex.org/work/W3097476988> ?p ?o ?g. }
Showing items 1 to 61 of
61
with 100 items per page.
- W3097476988 abstract "The reaction of aluminium hydroborate with alcohols and thiols is discussed, and this is extended to cover possible mechanisms for hydrolysis. The course of the reaction was found to be dependent on the structural type of alcohol or thiol used. Substitution of a thio alkyl group for hydroborate led to preparation of the type of compound RSA1(BH₄ )₂ (where R = methyl, ethyl, benzyl) and properties of these compounds are discussed. Using an exchange reaction of aluminium hydroborate with alkyl borates , corresponding compounds of the type RO Al(BH₄)₂ (R = methyl, ethyl) were prepared, and their properties ascertained.The behaviour of aluminium hydroborate with triethyl and trimethyl borane is considered. This work suggests that there is an exchange between the terminal hydrogens of the hydroborate groups and the borane alkyl groups, resultingin B-a!kylated aluminiumhydroborates. B-alkylated hydroborates a real so believed to be formed from a novel reaction between triethyl a lane and tetraethyl diborane.Some chemistryof the octahydrotriborate group linked to aluminium is also discussed. Starting from dimethyl aluminiumoctahydrotriborate an exchange reaction with excess aluminiumhydroborate yields aluminiumoctahydrotriborate bis hydroborate. The properties of both compounds are discussed, and the relevance of the latter to aluminium hydroborate decomposition is noted.The practical work involved extensive use of vacuum line and inert atmosphere techniques, and infra-red and n.m.r.spectral details were very useful." @default.
- W3097476988 created "2020-11-09" @default.
- W3097476988 creator A5032268507 @default.
- W3097476988 date "1978-09-01" @default.
- W3097476988 modified "2023-09-27" @default.
- W3097476988 title "An investigation of some reactions of aluminium hydroborate" @default.
- W3097476988 hasPublicationYear "1978" @default.
- W3097476988 type Work @default.
- W3097476988 sameAs 3097476988 @default.
- W3097476988 citedByCount "0" @default.
- W3097476988 crossrefType "dissertation" @default.
- W3097476988 hasAuthorship W3097476988A5032268507 @default.
- W3097476988 hasConcept C161790260 @default.
- W3097476988 hasConcept C178790620 @default.
- W3097476988 hasConcept C179104552 @default.
- W3097476988 hasConcept C185592680 @default.
- W3097476988 hasConcept C188027245 @default.
- W3097476988 hasConcept C2778072282 @default.
- W3097476988 hasConcept C2778826510 @default.
- W3097476988 hasConcept C2780263894 @default.
- W3097476988 hasConcept C2781253882 @default.
- W3097476988 hasConcept C501308230 @default.
- W3097476988 hasConcept C513153333 @default.
- W3097476988 hasConceptScore W3097476988C161790260 @default.
- W3097476988 hasConceptScore W3097476988C178790620 @default.
- W3097476988 hasConceptScore W3097476988C179104552 @default.
- W3097476988 hasConceptScore W3097476988C185592680 @default.
- W3097476988 hasConceptScore W3097476988C188027245 @default.
- W3097476988 hasConceptScore W3097476988C2778072282 @default.
- W3097476988 hasConceptScore W3097476988C2778826510 @default.
- W3097476988 hasConceptScore W3097476988C2780263894 @default.
- W3097476988 hasConceptScore W3097476988C2781253882 @default.
- W3097476988 hasConceptScore W3097476988C501308230 @default.
- W3097476988 hasConceptScore W3097476988C513153333 @default.
- W3097476988 hasLocation W30974769881 @default.
- W3097476988 hasOpenAccess W3097476988 @default.
- W3097476988 hasPrimaryLocation W30974769881 @default.
- W3097476988 hasRelatedWork W1969159020 @default.
- W3097476988 hasRelatedWork W1978823522 @default.
- W3097476988 hasRelatedWork W1979812018 @default.
- W3097476988 hasRelatedWork W1983487363 @default.
- W3097476988 hasRelatedWork W1989735940 @default.
- W3097476988 hasRelatedWork W1996544630 @default.
- W3097476988 hasRelatedWork W2006666940 @default.
- W3097476988 hasRelatedWork W2015151153 @default.
- W3097476988 hasRelatedWork W2029985525 @default.
- W3097476988 hasRelatedWork W2045133757 @default.
- W3097476988 hasRelatedWork W2048133498 @default.
- W3097476988 hasRelatedWork W2062212217 @default.
- W3097476988 hasRelatedWork W2080526116 @default.
- W3097476988 hasRelatedWork W2089628057 @default.
- W3097476988 hasRelatedWork W2090949069 @default.
- W3097476988 hasRelatedWork W2092286560 @default.
- W3097476988 hasRelatedWork W2143056450 @default.
- W3097476988 hasRelatedWork W2951665309 @default.
- W3097476988 hasRelatedWork W2979995887 @default.
- W3097476988 hasRelatedWork W71344103 @default.
- W3097476988 isParatext "false" @default.
- W3097476988 isRetracted "false" @default.
- W3097476988 magId "3097476988" @default.
- W3097476988 workType "dissertation" @default.