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- W3097695768 abstract "The [3,3]-sigmatropic allyl cyanate/isocyanate rearrangement of glycals in the presence of O-, N-, and C-nucleophiles afforded β-N-glucosyl and galactosyl carbamates, ureas, and amides in good yields. The unsaturated products were elaborated to N-glycosides by dihydroxylation, to 1,3-diaminosugars by tethered aminohydroxylation, or to 1,2-diaminosugars by iteration of the sigmatropic rearrangement. This metal-free methodology represents an excellent and general method for the stereoselective synthesis of N-glycosides and diamino sugars with complete transmission of stereochemical information." @default.
- W3097695768 created "2020-11-09" @default.
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- W3097695768 date "2020-11-04" @default.
- W3097695768 modified "2023-10-04" @default.
- W3097695768 title "Allyl Cyanate/Isocyanate Rearrangement in Glycals: Stereoselective Synthesis of 1-Amino and Diamino Sugar Derivatives" @default.
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- W3097695768 doi "https://doi.org/10.1021/acs.orglett.0c03438" @default.
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