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• W3098247954 abstract "Temperature-dependent synchrotron powder diffraction on Cs0.83(Fe0.86Se)2 revealed first-order I4/m to I4/mmm structural transformation around 216 °C associated with a disorder of the Fe vacancies. Irreversibility observed during the transition is likely associated with a mobility of the intercalated alkali atoms. Pressure-dependent synchrotron powder diffraction on Cs0.83(Fe1–ySe)2, Rb0.85(Fe1–ySe)2, and K0.8(Fe1–ySe)2 (y ∼ 0.14) indicated that the I4/m superstructure reflections are present up to pressures of 120 kbar. This may indicate that the ordering of the Fe vacancies is present in both superconducting and nonsuperconductive states." @default.
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• W3098247954 date "2011-10-11" @default.
• W3098247954 modified "2023-10-03" @default.
• W3098247954 title "Temperature and Pressure Evolution of the Crystal Structure of A_<i>x</i>(Fe_1–<i>y</i>Se)₂ (A = Cs, Rb, K) Studied by Synchrotron Powder Diffraction" @default.
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• W3098247954 doi "https://doi.org/10.1021/ic201160y" @default.
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