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• W3098522211 abstract "We propose an analytical method for solving the problem of barrierless reactions in solution, modeled by a particle undergoing diffusive motion under the influence of both reactant and product potentials. The coupling between these two potentials is taken to be a Dirac Delta function. The diffusive motion in this paper is described by the Smoluchowskii equation. Our solution requires only the knowledge of the Laplace transform of the Green's function for the motion in both the uncoupled potentials. Our model is more general than all the earlier models, because we are the first one to consider the potential energy surfaces of both the reactant and product explicitly." @default.
• W3098522211 created "2020-11-23" @default.
• W3098522211 creator A5006076143 @default.
• W3098522211 date "2013-09-03" @default.
• W3098522211 modified "2023-09-24" @default.
• W3098522211 title "Barrierless electronic relaxation in solution: An analytically solvable model" @default.
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• W3098522211 doi "https://doi.org/10.1063/1.4819403" @default.
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