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- W3098639968 abstract "Abstract Star‐shaped polymers have unique physical properties and they are sought after materials in industry. However, the ease of synthesis is essential for translation of these materials into large‐scale applications. Herein, a highly efficient synthetic method to prepare star‐shaped polymers by combination of Cu‐mediated reversible deactivation radical polymerization (Cu‐RDRP) and thiol‐bromo click reaction is described. Well‐defined linear and block polymers with a very high bromine chain end fidelity are obtained via Cu‐RDRP and subsequently react with multi‐functional thiol compounds. High coupling efficiencies of larger than 90% are obtained owing to the quick and efficient reaction between thiols and alkyl bromides. Moreover, the arms of the obtained star‐shaped polymers are linked via thioether bonds to the core, making them susceptible for oxidative degradation." @default.
- W3098639968 created "2020-11-23" @default.
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- W3098639968 date "2020-11-18" @default.
- W3098639968 modified "2023-10-01" @default.
- W3098639968 title "Thiol‐Bromo Click Reaction for One‐Pot Synthesis of Star‐Shaped Polymers" @default.
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- W3098639968 doi "https://doi.org/10.1002/marc.202000519" @default.
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