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• W3099162503 abstract "The low utilization efficiency in the visible region of the sunlight spectrum and the rapid recombination of photogenerated charge carriers are two crucial drawbacks that suppress the practical usage of metal oxide semiconductors as photocatalysts. In this article, we report a rational design of In2O3-In2S3 heterojunctions encapsulated by N-doped carbon with a hollow dodecahedral structure (In2O3-In2S3/N-C HDS), which can effectively handle the two drawbacks of metal oxide semiconductors and behave active for organic transformation under the irradiation of visible light even with long wavelengths. As exemplified by the selective oxidative coupling reaction of amine to imine, the obtained In2O3-In2S3/N-C HDS as the photocatalyst has exhibited excellent activity and stability. Experimental and density functional theory studies have verified that the excellent performance of In2O3-In2S3/N-C HDS can be attributed to the synergistic effect of In2O3-In2S3 heterojunctions, the coating of N-doped carbon, and the hollow porous structure with nanosheets as subunits." @default.
• W3099162503 created "2020-11-23" @default.
• W3099162503 creator A5002854208 @default.
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• W3099162503 date "2020-11-18" @default.
• W3099162503 modified "2023-10-16" @default.
• W3099162503 title "Hollow Dodecahedral Structure of In₂O₃-In₂S₃ Heterojunction Encapsulated by N-Doped C as an Excellent Visible-Light-Active Photocatalyst for Organic Transformation" @default.
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• W3099162503 doi "https://doi.org/10.1021/acs.inorgchem.0c02892" @default.
• W3099162503 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33206500" @default.
• W3099162503 hasPublicationYear "2020" @default.
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