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- W3099687310 abstract "2-Aminothiazoles have been synthesized by a one-pot, two-step sequential procedure in solution state which does not involve the isolation of intermediates. It involves α-halogenation of corresponding precursor ketones followed by condensation with substituted thiourea derivatives. All the products were analyzed by IR, NMR, mass spectral techniques and four of them were evaluated crystallographically. One of them crystallizes in the triclinic crystal system with space group P1¯, while, all the other compounds crystallize in the monoclinic crystal system in two different space groups viz. P21/c and P21/n. The modified 2-aminothiazole core did not show any change in the intermolecular interaction. The N-H…N interaction predominates over other interactions forming centrosymmetric head to head dimer with the neighboring atoms. This feature is observed in all the molecules except N-(4-(4-bromophenyl)-3-(2,5-dimethylphenyl)thiazol-2(3H)-ylidene)-2,5-dimethylaniline." @default.
- W3099687310 created "2020-11-23" @default.
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- W3099687310 date "2020-09-16" @default.
- W3099687310 modified "2023-10-12" @default.
- W3099687310 title "Sequential One-Pot Synthesis of 2-Aminothiazoles Using Corresponding Ketones: Insights into Their Structural Features" @default.
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- W3099687310 doi "https://doi.org/10.1080/10406638.2020.1821228" @default.
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