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• W3099808522 abstract "Ion associates (IA) of butylrodamine C with triiodide and iod bromide have been synthesized. Their thermal behavior is investigated. Thermolysis synthesized by IA BR+I3¯ passes through a number of intermediate stages, since the C4H9 radical, which is part of the dye, has a significant effect on the process of thermolysis of the ionic associate. IA BR+I3¯ begins to decompose significantly at a temperature higher than 140 єC with an endothermic effect at 240 єC and two small exothermic effects with a maximum at 282 єC and 355 єC (corresponding to the release of 2NH3, 8C2H4, 2HI). In the range of 380–720 єC, the exothermic effect of the IA combustion occurs at a temperature of 485 єC with significant mass loss. The obtained IAs are stable under normal conditions. An I3¯ and I2Br¯ sensor containing butyrodromine C associate of butylrodamine C with triiodide and iodum bromide was developed. The working interval of the pH of the triiodide sensor is 2 - 12, and for iodum bromide, the pH is 2 - 10, respectively. The linearity interval of the electrode function is in the range 9 ∙10-6 - 1 ∙10-1 mol L-1, the slope is 65 mV/pC for the triiodide, and for the iodine bromide - 1 ∙10-5 - 1 ∙10-1 mol L-1, the slope 68 mV/pC. The technique of potentiometric determination of analgin in medicines is developed." @default.
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• W3099808522 date "2020-01-01" @default.
• W3099808522 modified "2023-09-23" @default.
• W3099808522 title "Potentiometric Sensor For Analgin Determination In Pharmaceutical Formulations" @default.
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• W3099808522 doi "https://doi.org/10.17721/moca.2020.66-72" @default.
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