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- W3100156523 abstract "We develop a series of approximations to calculate free energy of a polar liquid. We show that long range nature of dipole interactions between the molecules leads to para-electric state instability at low temperatures and to a second-order phase transition. We establish the transition temperature, T_{c}, both within mean field and ring diagrams approximation and show that the ferro-electric transition may play an important role explaining a number of peculiar properties of supercooled water, such as weak singularity of dielectric constant as well as to a large extent anomalous density behavior. Finally we discuss the role of fluctuations, shorter range forces and establish connections with phenomenological models of polar liquids." @default.
- W3100156523 created "2020-11-23" @default.
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- W3100156523 date "2008-08-07" @default.
- W3100156523 modified "2023-09-27" @default.
- W3100156523 title "Ferro-electric phase transition in a polar liquid and the nature of lambda-transition in supercooled water" @default.
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