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• W3100157802 endingPage "364108" @default.
• W3100157802 startingPage "364108" @default.
• W3100157802 abstract "Thermodynamic properties of charge-stabilised colloidal suspensions are commonly modeled by implementing the mean-field Poisson-Boltzmann (PB) theory within a cell model. This approach models a bulk system by a single macroion, together with counterions and salt ions, confined to a symmetrically shaped, electroneutral cell. While easing solution of the nonlinear PB equation, the cell model neglects microion-induced correlations between macroions, precluding modeling of macroion ordering phenomena. An alternative approach, avoiding artificial constraints of cell geometry, maps a macroion-microion mixture onto a one-component model of pseudo-macroions governed by effective interactions. In practice, effective-interaction models are usually based on linear screening approximations, which can accurately describe nonlinear screening only by incorporating an effective (renormalized) macroion charge. Combining charge renormalization and linearized PB theories, in both the cell model and an effective-interaction (cell-free) model, we compute osmotic pressures of highly charged colloids and monovalent microions over a range of concentrations. By comparing predictions with primitive model simulation data for salt-free suspensions, and with predictions of nonlinear PB theory for salty suspensions, we chart the limits of both the cell model and linear-screening approximations in modeling bulk thermodynamic properties. Up to moderately strong electrostatic couplings, the cell model proves accurate in predicting osmotic pressures of deionized suspensions. With increasing salt concentration, however, the relative contribution of macroion interactions grows, leading predictions of the cell and effective-interaction models to deviate. No evidence is found for a liquid-vapour phase instability driven by monovalent microions. These results may guide applications of PB theory to soft materials." @default.
• W3100157802 created "2020-11-23" @default.
• W3100157802 creator A5041149702 @default.
• W3100157802 date "2010-08-20" @default.
• W3100157802 modified "2023-10-02" @default.
• W3100157802 title "Poisson–Boltzmann theory of charged colloids: limits of the cell model for salty suspensions" @default.
• W3100157802 cites W1505701304 @default.
• W3100157802 cites W1861850933 @default.
• W3100157802 cites W1966696598 @default.
• W3100157802 cites W1971986704 @default.
• W3100157802 cites W1976971282 @default.
• W3100157802 cites W1977707378 @default.
• W3100157802 cites W1978703672 @default.
• W3100157802 cites W1983966894 @default.
• W3100157802 cites W1985062737 @default.
• W3100157802 cites W1985249300 @default.
• W3100157802 cites W1985253338 @default.
• W3100157802 cites W1986081681 @default.
• W3100157802 cites W1989683268 @default.
• W3100157802 cites W1990708615 @default.
• W3100157802 cites W1994682438 @default.
• W3100157802 cites W1998910516 @default.
• W3100157802 cites W2000314192 @default.
• W3100157802 cites W2000989546 @default.
• W3100157802 cites W2001581695 @default.
• W3100157802 cites W2002980324 @default.
• W3100157802 cites W2003312209 @default.
• W3100157802 cites W2004976458 @default.
• W3100157802 cites W2005448985 @default.
• W3100157802 cites W2011794432 @default.
• W3100157802 cites W2011957182 @default.
• W3100157802 cites W2012118687 @default.
• W3100157802 cites W2014428300 @default.
• W3100157802 cites W2017222585 @default.
• W3100157802 cites W2019277914 @default.
• W3100157802 cites W2020183368 @default.
• W3100157802 cites W2022630982 @default.
• W3100157802 cites W2022840857 @default.
• W3100157802 cites W2025256593 @default.
• W3100157802 cites W2026482940 @default.
• W3100157802 cites W2029039540 @default.
• W3100157802 cites W2029426692 @default.
• W3100157802 cites W2031189120 @default.
• W3100157802 cites W2032326831 @default.
• W3100157802 cites W2036203264 @default.
• W3100157802 cites W2037251547 @default.
• W3100157802 cites W2037581237 @default.
• W3100157802 cites W2038948513 @default.
• W3100157802 cites W2040698114 @default.
• W3100157802 cites W2042884243 @default.
• W3100157802 cites W2051674182 @default.
• W3100157802 cites W2054967121 @default.
• W3100157802 cites W2056972872 @default.
• W3100157802 cites W2058517883 @default.
• W3100157802 cites W2058638252 @default.
• W3100157802 cites W2059523289 @default.
• W3100157802 cites W2061049862 @default.
• W3100157802 cites W2064317054 @default.
• W3100157802 cites W2064930022 @default.
• W3100157802 cites W2067048994 @default.
• W3100157802 cites W2067946856 @default.
• W3100157802 cites W2068969153 @default.
• W3100157802 cites W2069505941 @default.
• W3100157802 cites W2072348763 @default.
• W3100157802 cites W2076762290 @default.
• W3100157802 cites W2077809249 @default.
• W3100157802 cites W2082319296 @default.
• W3100157802 cites W2087846839 @default.
• W3100157802 cites W2090962338 @default.
• W3100157802 cites W2092340579 @default.
• W3100157802 cites W2093328507 @default.
• W3100157802 cites W2096252726 @default.
• W3100157802 cites W2100432652 @default.
• W3100157802 cites W2103543844 @default.
• W3100157802 cites W2108205854 @default.
• W3100157802 cites W2113295320 @default.
• W3100157802 cites W2115011796 @default.
• W3100157802 cites W2118301109 @default.
• W3100157802 cites W2127091213 @default.
• W3100157802 cites W2134172817 @default.
• W3100157802 cites W2142737051 @default.
• W3100157802 cites W2161366630 @default.
• W3100157802 cites W2162246191 @default.
• W3100157802 cites W2163448702 @default.
• W3100157802 cites W2963050658 @default.
• W3100157802 cites W2963579394 @default.
• W3100157802 cites W3098084504 @default.
• W3100157802 cites W3098099845 @default.
• W3100157802 cites W3098579552 @default.
• W3100157802 cites W3099272554 @default.
• W3100157802 cites W3104714087 @default.
• W3100157802 cites W3105984713 @default.
• W3100157802 cites W4243760921 @default.
• W3100157802 cites W84411913 @default.
• W3100157802 doi "https://doi.org/10.1088/0953-8984/22/36/364108" @default.
• W3100157802 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21386524" @default.
• W3100157802 hasPublicationYear "2010" @default.
• W3100157802 type Work @default.

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