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• W3100266953 abstract "Experiments on single crystal ${mathrm{Li}}_{X}{mathrm{FePO}}_{4}$ nanoparticles indicate rich nonequilibrium phase behavior, such as suppression of phase separation at high lithiation rates, striped patterns of coherent phase boundaries, and nucleation by binary-solid surface wetting and intercalation waves. These observations have been successfully predicted (prior to the experiments) by one-dimensional (1D) depth-averaged phase-field models, which neglect any subsurface phase separation. In this paper, using an electro-chemo-mechanical phase-field model, we investigate the coherent nonequilibrium subsurface phase morphologies that develop in the $ab$ plane of plateletlike single-crystal plateletlike ${mathrm{Li}}_{X}{mathrm{FePO}}_{4}$ nanoparticles. Finite element 2D plane-stress and plane-strain simulations are performed in the $ab$ plane and validated by 3D simulations, showing similar results. Using a realistic material model from previous work, we show that the anisotropy of the interfacial tension (or gradient penalty) tensor and its relation to electro-auto-catalytic surface intercalation reactions plays a crucial role in determining the subsurface phase morphology. With the standard assumption of an isotropic interfacial tension tensor, subsurface phase separation in the bulk is observed and its morphology is independent of the reaction kinetics at the surface, but for strong anisotropy, phase separation is controlled by surface reactions, as assumed in 1D models. Moreover, the driven intercalation reaction suppresses phase separation during lithiation, while enhancing it during delithiation, by electro-auto-catalysis, in quantitative agreement with in operando imaging experiments in single-crystalline nanoparticles, given measured reaction rate constants." @default.
• W3100266953 created "2020-11-23" @default.
• W3100266953 creator A5001562932 @default.
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• W3100266953 creator A5070486479 @default.
• W3100266953 date "2018-08-16" @default.
• W3100266953 modified "2023-09-30" @default.
• W3100266953 title "Interplay of phase boundary anisotropy and electro-auto-catalytic surface reactions on the lithium intercalation dynamics in <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:msub><mml:mi>Li</mml:mi><mml:mi>X</mml:mi></mml:msub><mml:msub><mml:mi>FePO</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:mrow></mml:math> plateletlike nanoparticles" @default.
• W3100266953 cites W1530537400 @default.
• W3100266953 cites W1669109950 @default.
• W3100266953 cites W1855644029 @default.
• W3100266953 cites W1967142014 @default.
• W3100266953 cites W1968508314 @default.
• W3100266953 cites W1968896353 @default.
• W3100266953 cites W1975642004 @default.
• W3100266953 cites W1977032047 @default.
• W3100266953 cites W1994402496 @default.
• W3100266953 cites W1999604713 @default.
• W3100266953 cites W2000118505 @default.
• W3100266953 cites W2001270915 @default.
• W3100266953 cites W2007272229 @default.
• W3100266953 cites W2008307972 @default.
• W3100266953 cites W2008631597 @default.
• W3100266953 cites W2010251226 @default.
• W3100266953 cites W2010306601 @default.
• W3100266953 cites W2015165346 @default.
• W3100266953 cites W2015475877 @default.
• W3100266953 cites W2024565483 @default.
• W3100266953 cites W2030247238 @default.
• W3100266953 cites W2040931463 @default.
• W3100266953 cites W2041108396 @default.
• W3100266953 cites W2042096243 @default.
• W3100266953 cites W2043647983 @default.
• W3100266953 cites W2045759452 @default.
• W3100266953 cites W2046528357 @default.
• W3100266953 cites W2054662898 @default.
• W3100266953 cites W2057482274 @default.
• W3100266953 cites W2058484299 @default.
• W3100266953 cites W2066273617 @default.
• W3100266953 cites W2070159662 @default.
• W3100266953 cites W2074439496 @default.
• W3100266953 cites W2075527366 @default.
• W3100266953 cites W2078211541 @default.
• W3100266953 cites W2084080017 @default.
• W3100266953 cites W2085168012 @default.
• W3100266953 cites W2090500591 @default.
• W3100266953 cites W2094627446 @default.
• W3100266953 cites W2105826995 @default.
• W3100266953 cites W2107966203 @default.
• W3100266953 cites W2111868374 @default.
• W3100266953 cites W2113449668 @default.
• W3100266953 cites W2117999728 @default.
• W3100266953 cites W2124097995 @default.
• W3100266953 cites W2130836970 @default.
• W3100266953 cites W2130893993 @default.
• W3100266953 cites W2133901121 @default.
• W3100266953 cites W2149815190 @default.
• W3100266953 cites W2153230371 @default.
• W3100266953 cites W2169727828 @default.
• W3100266953 cites W2260433152 @default.
• W3100266953 cites W2267637650 @default.
• W3100266953 cites W2274551396 @default.
• W3100266953 cites W2315945022 @default.
• W3100266953 cites W2322804870 @default.
• W3100266953 cites W2326687709 @default.
• W3100266953 cites W2330548279 @default.
• W3100266953 cites W2412023093 @default.
• W3100266953 cites W2477016625 @default.
• W3100266953 cites W2569713119 @default.
• W3100266953 cites W2778176744 @default.
• W3100266953 cites W2783771551 @default.
• W3100266953 cites W2964245245 @default.
• W3100266953 cites W3099746599 @default.
• W3100266953 cites W3101622497 @default.
• W3100266953 cites W3102404986 @default.
• W3100266953 cites W3103904046 @default.
• W3100266953 cites W3106397231 @default.
• W3100266953 cites W3123452468 @default.
• W3100266953 cites W4229878554 @default.
• W3100266953 doi "https://doi.org/10.1103/physrevmaterials.2.085406" @default.
• W3100266953 hasPublicationYear "2018" @default.
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