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• W3100332520 endingPage "86" @default.
• W3100332520 startingPage "81" @default.
• W3100332520 abstract "Promising pathways for photoassociative formation of ultracold heteronuclear alkali metal dimers in their lowest rovibronic levels (denoted X(0,0)) are examined using high quality ab initio calculations of potential energy curves currently available. A promising pathway for KRb, involving the resonant coupling of the $2 ^1Pi$ and $1 ^1Pi $ states just below the lowest excited asymptote (K($4s$)+Rb($5p_{1/2}$)), is found to occur also for RbCs and less promisingly for KCs as well. The resonant coupling of the $3 ^1 Sigma ^+ $ and $1 ^1Pi $ states, also just below the lowest excited asymptote, is found to be promising for LiNa, LiK, LiRb, and less promising for LiCs and KCs. Direct photoassociation to the $1 ^1Pi $ state near dissociation appears promising in the final dimers, NaK, NaRb, and NaCs, although detuning more than 100 cm$^{-1}$ below the lowest excited asymptote may be required." @default.
• W3100332520 created "2020-11-23" @default.
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• W3100332520 date "2009-12-07" @default.
• W3100332520 modified "2023-09-26" @default.
• W3100332520 title "Resonant Coupling in the Heteronuclear Alkali Dimers for Direct Photoassociative Formation of X(0,0) Ultracold Molecules" @default.
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• W3100332520 doi "https://doi.org/10.1021/jp901803f" @default.
• W3100332520 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19968307" @default.
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