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- W3100335926 abstract "Aluminum is the third most abundant element in Earth’s crust (8.3% in mass), behind oxygen (45.5%) and silicon (27.2%). It forms in nature various oxygenated mineral phases: hydroxides Al(OH)3, oxyhydroxides AlOOH, of which bauxite is the main ore, and oxides, Al2O3, alumina. Corundum, α- Al2O3, is the component of many gems: sapphire (pure Al2O3, perfectly colorless), ruby (red colored due to the presence of Cr3+ ions), and blue sapphire (blue colored by the presence of Ti4+ and Fe2+ ions), among many others. The content of foreign elements substituted for Al3+ ions in these phases accounts for only a small percentage of the total. Aluminum also forms many natural phases in combination with various elements, especially silicon in aluminosilicates, such as feldspars, clays, zeolites, allophanes, and imogolites. The biochemical cycling of the elements involves many soluble complexes of aluminum in natural waters [1, 2]. Aluminum oxides and oxy(hydroxi)des are important materials and nanomaterials used in many fields: for instance, as active phase for adsorption in water treatment; as inert support and active phase in catalysis; as active phase in flame-retardant polymers; as refractory material for laboratory tools and in the ceramics industry; and as abrasives [3, 4]. Alumina Al2O3 is produced in various forms (tubes, balls, fibers, and powders) for numerous industrial uses (laboratory tools, filtration membranes, ball bearings, fine powders as catalysis supports, etc.). The structural chemistry of aluminum oxy(hydroxi)des is rich. There are various hydroxides, Al(OH)3 (gibbsite, also named hydrargillite, bayerite, and some other polytypes such as nordstrandite and doyleite), oxyhydroxides, AlOOH (boehmite and diaspore), and a series of oxides, Al2O3, so-called transition aluminas. These last phases have different degrees of hydration and different degrees of order of the Al3+ cations within the cubic close packing of oxygen atoms according to the temperature at which they have been submitted. They belong to various structural types (γ, δ, θ, η, κ, etc.). These aluminas of huge specific surface areas are usually used in catalysis, especially γ-alumina of spinel crystal structure." @default.
- W3100335926 created "2020-11-23" @default.
- W3100335926 creator A5053553541 @default.
- W3100335926 date "2019-02-28" @default.
- W3100335926 modified "2023-09-26" @default.
- W3100335926 title "Aluminum Oxides: Alumina and Aluminosilicates" @default.
- W3100335926 doi "https://doi.org/10.1093/oso/9780190928117.003.0009" @default.
- W3100335926 hasPublicationYear "2019" @default.
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