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- W3100339973 abstract "Ba4NbIr3O12, a previously unreported material with a triangular planar geometry of Ir3O12 trimers, is described. Magnetic susceptibility measurements show no magnetic ordering down to 1.8 K despite the Curie-Weiss temperature of -13 K. The material has a very low effective magnetic moment of 0.80 {mu}B/f.u. To look at the lower temperature behavior, the specific heat (Cp) was measured down to 0.35 K; it shows no indication of magnetic ordering and fitting a power law to Cp vs. T below 2 K yields the power {alpha} = 3/4. Comparison to the previously unreported trimer compound made with the 4d element Rh in place of the 5d element Ir, Ba4NbRh3O12, is presented. The analysis suggests that Ba4NbIr3O12 is a candidate spin liquid material." @default.
- W3100339973 created "2020-11-23" @default.
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- W3100339973 date "2019-01-23" @default.
- W3100339973 modified "2023-09-26" @default.
- W3100339973 title "Trimer-based spin liquid candidate <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:mi mathvariant=normal>B</mml:mi><mml:msub><mml:mi mathvariant=normal>a</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:mi>NbI</mml:mi><mml:msub><mml:mi mathvariant=normal>r</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>12</mml:mn></mml:msub></mml:mrow></mml:math>" @default.
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- W3100339973 doi "https://doi.org/10.1103/physrevmaterials.3.014412" @default.
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