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- W3100374220 endingPage "754" @default.
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- W3100374220 abstract "We report the presence of sigma-aromaticity in a surface deposited cluster, Pd$_4$ on TiO$_2$ (110). In the gas phase, Pd$_4$ adopts a tetrahedral structure. However, surface binding promotes a flat, sigma-aromatic cluster. This is the first time aromaticity is found in surface deposited clusters. Systems of this type emerge as a promising class of catalyst, and so realization of aromaticity in them may help to rationalize their reactivity and catalytic properties, as a function of cluster size and composition." @default.
- W3100374220 created "2020-11-23" @default.
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- W3100374220 date "2012-03-01" @default.
- W3100374220 modified "2023-10-18" @default.
- W3100374220 title "Double σ-Aromaticity in a Surface-Deposited Cluster: Pd<sub>4</sub> on TiO<sub>2</sub> (110)" @default.
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- W3100374220 doi "https://doi.org/10.1021/jz300158s" @default.
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