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- W3100406413 abstract "Abstract The deliberate surface modification of nanocatalysts with organic ligands has recently emerged as a promising strategy to boost their efficiency, durability, and/or selectivity in key electrocatalytic processes. The interface between the metallic interface and the immobilized ligands promotes high electrocatalytic activity. Herein, the oxygen reduction reaction activity of gold nanoparticles functionalized with a covalently bound monolayer of calix[4]arenes is compared with commercially available gold nanoparticles, classically stabilized through electrostatic adsorption of citrates onto the gold surfaces. Nanocatalysts coated by calix[4]arenes show enhanced selectivity and stability compared to their citrate‐stabilized counterparts. These nanohybrids exhibit excellent activity with a dominant 4‐electron reduction of O 2 with good electrocatalytic performances along with a high robustness under operation as revealed by X‐ray photoelectron spectroscopy analyses." @default.
- W3100406413 created "2020-11-23" @default.
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- W3100406413 date "2020-11-12" @default.
- W3100406413 modified "2023-10-16" @default.
- W3100406413 title "Functionalizing Gold Nanoparticles with Calix[4]arenes Monolayers for Enhancing Selectivity and Stability in ORR Electrocatalysis" @default.
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- W3100406413 doi "https://doi.org/10.1002/admi.202001557" @default.
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