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• W3100414063 abstract "Raman spectra and electrical conductance of individual, pristine, suspended, metallic single-walled carbon nanotubes are measured under applied gate potentials. The G- band is observed to downshift with small applied gate voltages, with the minima occurring at EF = +/- 1/2 Ephonon, contrary to adiabatic predictions. A subsequent upshift in the Raman frequency at higher gate voltages results in a 'W'-shaped Raman shift profile that agrees well with a non-adiabatic phonon renormalization model. This behavior constitutes the first experimental confirmation of the theoretically predicted breakdown of the Born-Oppenheimer approximation in individual single walled carbon nanotubes." @default.
• W3100414063 created "2020-11-23" @default.
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• W3100414063 date "2009-01-22" @default.
• W3100414063 modified "2023-10-15" @default.
• W3100414063 title "Direct Observation of Born−Oppenheimer Approximation Breakdown in Carbon Nanotubes" @default.
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• W3100414063 doi "https://doi.org/10.1021/nl802854x" @default.
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