FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3100459240> ?p ?o ?g. }

• W3100459240 endingPage "53393" @default.
• W3100459240 startingPage "53385" @default.
• W3100459240 abstract "In recent years, metal-organic frameworks (MOFs) have been explored as emulsifiers for the fabrication of Pickering emulsions and then used for hybrid material synthesis and interface catalysis. Nevertheless, stimuli-responsive Pickering emulsions stabilized by MOFs have been rarely reported so far, although they are of great importance for fundamental research studies and practical applications. Herein, for the first time, triethylenetetramine (TETA)-functionalized MOFs (ZIF-90/TETA) have been designed, synthesized, and used for fabricating CO2-/N2-response Pickering emulsions. It is shown that even at the ZIF-90/TETA content of 0.25 wt %, the functional MOF can still efficiently emulsify n-hexane and water to form a high internal phase Pickering emulsion. Importantly, the Pickering emulsion can be easily and reversibly switched between emulsification and demulsification by bubbling of CO2 and N2 alternatively at atmospheric pressure. The possible mechanism of the CO2/N2 switchable emulsion is investigated by zeta potential, water contact angle, interfacial tension, 13C NMR spectroscopy, and an optical microscope. It is found that the acid-base reaction of CO2 with TETA anchored on the surface of ZIF-90 leads to the production of hydrophilic ammonium bicarbonate and carbamate, which results in the emulsification of the Pickering emulsion. However, when N2 is bubbled to remove CO2, the reverse reaction takes place to cause the demulsification of the Pickering emulsion. Moreover, the CO2/N2 switchable Pickering emulsion has been successfully used as a microreactor for Knoevenagel reactions to demonstrate a highly efficient integration of chemical reaction, product separation, and ZIF-90/TETA recycling for a sustainable chemical process." @default.
• W3100459240 created "2020-11-23" @default.
• W3100459240 creator A5003078964 @default.
• W3100459240 creator A5027696701 @default.
• W3100459240 creator A5028304790 @default.
• W3100459240 creator A5045392802 @default.
• W3100459240 creator A5064644245 @default.
• W3100459240 creator A5079563573 @default.
• W3100459240 date "2020-11-10" @default.
• W3100459240 modified "2023-10-08" @default.
• W3100459240 title "Ambient CO₂/N₂ Switchable Pickering Emulsion Emulsified by TETA-Functionalized Metal–Organic Frameworks" @default.
• W3100459240 cites W1677747913 @default.
• W3100459240 cites W1917072535 @default.
• W3100459240 cites W1975117973 @default.
• W3100459240 cites W1975750858 @default.
• W3100459240 cites W1978580387 @default.
• W3100459240 cites W2004550299 @default.
• W3100459240 cites W2006030639 @default.
• W3100459240 cites W2009949442 @default.
• W3100459240 cites W2019719887 @default.
• W3100459240 cites W2029643095 @default.
• W3100459240 cites W2033342037 @default.
• W3100459240 cites W2043184909 @default.
• W3100459240 cites W2055976008 @default.
• W3100459240 cites W2065541627 @default.
• W3100459240 cites W2071650674 @default.
• W3100459240 cites W2074067370 @default.
• W3100459240 cites W2082179062 @default.
• W3100459240 cites W2086782801 @default.
• W3100459240 cites W2094509875 @default.
• W3100459240 cites W2099486431 @default.
• W3100459240 cites W2107991409 @default.
• W3100459240 cites W2109773325 @default.
• W3100459240 cites W2121068874 @default.
• W3100459240 cites W2122323849 @default.
• W3100459240 cites W2141939342 @default.
• W3100459240 cites W2166195832 @default.
• W3100459240 cites W2224551666 @default.
• W3100459240 cites W2291594029 @default.
• W3100459240 cites W2296514273 @default.
• W3100459240 cites W2299529061 @default.
• W3100459240 cites W2313798780 @default.
• W3100459240 cites W2316133297 @default.
• W3100459240 cites W2320034594 @default.
• W3100459240 cites W2326890574 @default.
• W3100459240 cites W2328282365 @default.
• W3100459240 cites W2334910708 @default.
• W3100459240 cites W2344516280 @default.
• W3100459240 cites W2401030480 @default.
• W3100459240 cites W2511822851 @default.
• W3100459240 cites W2527752201 @default.
• W3100459240 cites W2535526363 @default.
• W3100459240 cites W2555358155 @default.
• W3100459240 cites W2561011185 @default.
• W3100459240 cites W2750872686 @default.
• W3100459240 cites W2757819452 @default.
• W3100459240 cites W2766366232 @default.
• W3100459240 cites W2788165378 @default.
• W3100459240 cites W2792496226 @default.
• W3100459240 cites W2793465144 @default.
• W3100459240 cites W2858547974 @default.
• W3100459240 cites W2895093616 @default.
• W3100459240 cites W2896629605 @default.
• W3100459240 cites W2898109557 @default.
• W3100459240 cites W2907433615 @default.
• W3100459240 cites W2914421461 @default.
• W3100459240 cites W2944387567 @default.
• W3100459240 cites W2997325928 @default.
• W3100459240 cites W3015440696 @default.
• W3100459240 cites W3019426322 @default.
• W3100459240 cites W3037957623 @default.
• W3100459240 cites W3087531574 @default.
• W3100459240 cites W4231609898 @default.
• W3100459240 cites W4241218155 @default.
• W3100459240 cites W4244506205 @default.
• W3100459240 doi "https://doi.org/10.1021/acsami.0c13157" @default.
• W3100459240 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33170635" @default.
• W3100459240 hasPublicationYear "2020" @default.
• W3100459240 type Work @default.
• W3100459240 sameAs 3100459240 @default.
• W3100459240 citedByCount "27" @default.
• W3100459240 countsByYear W31004592402021 @default.
• W3100459240 countsByYear W31004592402022 @default.
• W3100459240 countsByYear W31004592402023 @default.
• W3100459240 crossrefType "journal-article" @default.
• W3100459240 hasAuthorship W3100459240A5003078964 @default.
• W3100459240 hasAuthorship W3100459240A5027696701 @default.
• W3100459240 hasAuthorship W3100459240A5028304790 @default.
• W3100459240 hasAuthorship W3100459240A5045392802 @default.
• W3100459240 hasAuthorship W3100459240A5064644245 @default.
• W3100459240 hasAuthorship W3100459240A5079563573 @default.
• W3100459240 hasConcept C127413603 @default.
• W3100459240 hasConcept C155672457 @default.
• W3100459240 hasConcept C159985019 @default.
• W3100459240 hasConcept C171250308 @default.
• W3100459240 hasConcept C178790620 @default.
• W3100459240 hasConcept C185592680 @default.
• W3100459240 hasConcept C192562407 @default.

• next