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• W3100486567 endingPage "315" @default.
• W3100486567 startingPage "305" @default.
• W3100486567 abstract "Exfoliation of layered materials provides nanosheets, such as monolayers and few-layers. In recent years, nanosheets have attracted much interest as two-dimensional (2D) materials for their diverse properties and applications originating from the anisotropic characteristic structures. Exfoliation methods have been developed depending on the types of interactions between the layers, such as van der Waals and electrostatic interactions. The present review focuses on exfoliation chemistry based on rigid and soft natures of the layered materials. The rigid inorganic layered compounds are converted to the soft layered materials with interaction of organic guests. The surface-functionalized nanosheets are obtained by exfoliation of the soft layered composites with dispersion in organic media. The exfoliation behavior is governed by the flexibility of the precursor layered materials, i.e. interaction between the interlayer guest and dispersion medium. Although exfoliation is generally an uncontrollable top-down process, materials informatics on our own experimental small data assists elucidation of the control factors toward tailored 2D materials. The exfoliation schemes are applied to a variety of layered materials. The present review shows potential new insights for exfoliation chemistry of soft layered materials. Exfoliation of layered materials provides nanosheets, such as monolayers and few-layers. The present review focuses on new exfoliation chemistry based on soft layered materials and materials informatics. Although exfoliation is generally an uncontrollable top-down process, the present approach has potentials for control of the exfoliation behavior." @default.
• W3100486567 created "2020-11-23" @default.
• W3100486567 creator A5036946471 @default.
• W3100486567 date "2021-02-05" @default.
• W3100486567 modified "2023-10-15" @default.
• W3100486567 title "Exfoliation Chemistry of Soft Layered Materials toward Tailored 2D Materials" @default.
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