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- W3100532548 abstract "Improved results using a method similar to the Munn−Silbey approach have been obtained on the temperature dependence of transport properties of an extended Holstein model incorporating simultaneous diagonal and off-diagonal exciton−phonon coupling. The Hamiltonian is partially diagonalized by a canonical transformation, and optimal transformation coefficients are determined in a self-consistent manner. Calculated transport properties exhibit substantial corrections on those obtained previously by Munn and Silbey for a wide range of temperatures thanks to a numerically exact evaluation and an added momentum-dependence of the transformation matrix. Results on the diffusion coefficient in the moderate and weak coupling regime show distinct band-like and hopping-like transport features as a function of temperature." @default.
- W3100532548 created "2020-11-23" @default.
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- W3100532548 date "2011-02-03" @default.
- W3100532548 modified "2023-10-02" @default.
- W3100532548 title "On the Munn−Silbey Approach to Polaron Transport with Off-Diagonal Coupling and Temperature-Dependent Canonical Transformations" @default.
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- W3100532548 doi "https://doi.org/10.1021/jp1093492" @default.
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