Matches in SemOpenAlex for { <https://semopenalex.org/work/W3100557930> ?p ?o ?g. }
- W3100557930 endingPage "245" @default.
- W3100557930 startingPage "239" @default.
- W3100557930 abstract "Abstract Since the discovery of the “living” free‐radical polymerization, alkoxyamines were widely used in nitroxide‐mediated polymerization (NMP). Most of the known alkoxyamines bear just one functionality with only a few exceptions bearing two or more alkoxyamine units. Herein, we present a library of novel multidimensional alkoxyamines based on commercially available, rigid, aromatic core structures. A versatile approach allows the introduction of different sidechains which have an impact on the steric hindrance and dissociation behavior of the alkoxyamines. The reaction to the alkoxyamines was optimized by implementing a mild and reliable procedure to give all target compounds in high yields. Utilization of biphenyl, p‐ terphenyl, 1,3,5‐triphenylbenzene, tetraphenylethylene, and tetraphenyl‐methane results in linear, trigonal, square planar, and tetrahedral shaped alkoxyamines. These building blocks are useful initiators for multifold NMP leading to star‐shaped polymers or as a linker for the nitroxide exchange reaction (NER), to obtain dynamic frameworks with a tunable crosslinking degree and self‐healing abilities." @default.
- W3100557930 created "2020-11-23" @default.
- W3100557930 creator A5004817738 @default.
- W3100557930 creator A5038053043 @default.
- W3100557930 creator A5052144587 @default.
- W3100557930 creator A5057298937 @default.
- W3100557930 creator A5088566997 @default.
- W3100557930 date "2020-12-16" @default.
- W3100557930 modified "2023-10-12" @default.
- W3100557930 title "Rigid Multidimensional Alkoxyamines: A Versatile Building Block Library" @default.
- W3100557930 cites W1967299069 @default.
- W3100557930 cites W1968922359 @default.
- W3100557930 cites W1970830396 @default.
- W3100557930 cites W1975558415 @default.
- W3100557930 cites W1976513995 @default.
- W3100557930 cites W1979608044 @default.
- W3100557930 cites W1981728874 @default.
- W3100557930 cites W1989825686 @default.
- W3100557930 cites W1991271765 @default.
- W3100557930 cites W1993193277 @default.
- W3100557930 cites W2000520136 @default.
- W3100557930 cites W2006561351 @default.
- W3100557930 cites W2010796936 @default.
- W3100557930 cites W2011480110 @default.
- W3100557930 cites W2012115416 @default.
- W3100557930 cites W2014740266 @default.
- W3100557930 cites W2031470320 @default.
- W3100557930 cites W2033413352 @default.
- W3100557930 cites W2035156915 @default.
- W3100557930 cites W2047931233 @default.
- W3100557930 cites W2052304852 @default.
- W3100557930 cites W2057744041 @default.
- W3100557930 cites W2064517255 @default.
- W3100557930 cites W2069364583 @default.
- W3100557930 cites W2069841520 @default.
- W3100557930 cites W2081361953 @default.
- W3100557930 cites W2100410379 @default.
- W3100557930 cites W2120410081 @default.
- W3100557930 cites W2144735746 @default.
- W3100557930 cites W2154760854 @default.
- W3100557930 cites W2163029681 @default.
- W3100557930 cites W2202733609 @default.
- W3100557930 cites W2404934389 @default.
- W3100557930 cites W2416152810 @default.
- W3100557930 cites W2438043034 @default.
- W3100557930 cites W2784604657 @default.
- W3100557930 cites W2808328026 @default.
- W3100557930 cites W2905000467 @default.
- W3100557930 cites W3009650511 @default.
- W3100557930 cites W3022937218 @default.
- W3100557930 cites W4211152539 @default.
- W3100557930 doi "https://doi.org/10.1002/ejoc.202001415" @default.
- W3100557930 hasPublicationYear "2020" @default.
- W3100557930 type Work @default.
- W3100557930 sameAs 3100557930 @default.
- W3100557930 citedByCount "2" @default.
- W3100557930 countsByYear W31005579302021 @default.
- W3100557930 countsByYear W31005579302022 @default.
- W3100557930 crossrefType "journal-article" @default.
- W3100557930 hasAuthorship W3100557930A5004817738 @default.
- W3100557930 hasAuthorship W3100557930A5038053043 @default.
- W3100557930 hasAuthorship W3100557930A5052144587 @default.
- W3100557930 hasAuthorship W3100557930A5057298937 @default.
- W3100557930 hasAuthorship W3100557930A5088566997 @default.
- W3100557930 hasBestOaLocation W31005579301 @default.
- W3100557930 hasConcept C111998727 @default.
- W3100557930 hasConcept C169912494 @default.
- W3100557930 hasConcept C178790620 @default.
- W3100557930 hasConcept C185592680 @default.
- W3100557930 hasConcept C188027245 @default.
- W3100557930 hasConcept C201194858 @default.
- W3100557930 hasConcept C21951064 @default.
- W3100557930 hasConcept C44228677 @default.
- W3100557930 hasConcept C521977710 @default.
- W3100557930 hasConceptScore W3100557930C111998727 @default.
- W3100557930 hasConceptScore W3100557930C169912494 @default.
- W3100557930 hasConceptScore W3100557930C178790620 @default.
- W3100557930 hasConceptScore W3100557930C185592680 @default.
- W3100557930 hasConceptScore W3100557930C188027245 @default.
- W3100557930 hasConceptScore W3100557930C201194858 @default.
- W3100557930 hasConceptScore W3100557930C21951064 @default.
- W3100557930 hasConceptScore W3100557930C44228677 @default.
- W3100557930 hasConceptScore W3100557930C521977710 @default.
- W3100557930 hasFunder F4320309895 @default.
- W3100557930 hasIssue "2" @default.
- W3100557930 hasLocation W31005579301 @default.
- W3100557930 hasLocation W31005579302 @default.
- W3100557930 hasOpenAccess W3100557930 @default.
- W3100557930 hasPrimaryLocation W31005579301 @default.
- W3100557930 hasRelatedWork W1968652470 @default.
- W3100557930 hasRelatedWork W1988970375 @default.
- W3100557930 hasRelatedWork W1997544452 @default.
- W3100557930 hasRelatedWork W2002636890 @default.
- W3100557930 hasRelatedWork W2005790235 @default.
- W3100557930 hasRelatedWork W2021250811 @default.
- W3100557930 hasRelatedWork W2039571086 @default.
- W3100557930 hasRelatedWork W2053404473 @default.
- W3100557930 hasRelatedWork W2075850793 @default.