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- W3100592323 abstract "The symmetrized contribution of E-type spin-rotation interaction to conversion between spin modifications of E- and A1-types in molecules with C3v-symmetry is considered. Using the high-J descending of collisional broadening for accidental rotational resonances between these spin modifications, it was possible to co-ordinate the theoretical description of the conversion with (updated) experimental data for two carbon-substituted isotopes of fluoromethane. As a result, both E-type spin-rotation constants are obtained. They are roughly one and a half times more than the corresponding constants for (deutero)methane." @default.
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- W3100592323 date "1999-01-01" @default.
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- W3100592323 title "On the spin-rotation contribution to nuclear spin conversion in C3v-symmetry molecules. Application to CH3F" @default.
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- W3100592323 doi "https://doi.org/10.1088/0953-4075/32/12/314" @default.
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