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- W3100613131 abstract "<i>Context. <i/>Astronomical observations toward Sagittarius B2(M) as well as other sources with APEX have recently suggested that the rest frequency of the <i>J<i/> = 1–0 transitions of <sup>13<sup/>CH<sup>+<sup/> is too low by about 80 MHz.<i>Aims. <i/>Improved rest frequencies of isotopologs of methylidynium should be derived to support analyses of spectral recording obtained with the ongoing <i>Herschel<i/> mission or the upcoming SOFIA.<i>Methods. <i/>Laboratory electronic spectra of four isotopologs of CH<sup>+<sup/> have been subjected to one global least-squares fit. Laboratory data for the <i>J<i/> = 1–0 ground state rotational transitions of CH<sup>+<sup/>, <sup>13<sup/>CH<sup>+<sup/>, and CD<sup>+<sup/>, which became available during the refereeing process, have been included in the fit as well.<i>Results. <i/>An accurate set of spectroscopic parameters has been obtained together with equilibrium bond lengths and accurate rest frequencies for six CH<sup>+<sup/> isotopologs: CH<sup>+<sup/>, <sup>13<sup/>CH<sup>+<sup/>, <sup>13<sup/>CD<sup>+<sup/>, CD<sup>+<sup/>, <sup>14<sup/>CH<sup>+<sup/>, and CT<sup>+<sup/>.<i>Conclusions. <i/>The present data will be useful for the analyses of <i>Herschel<i/> or SOFIA observations of methylidynium isotopic species." @default.
- W3100613131 created "2020-11-23" @default.
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- W3100613131 date "2010-05-01" @default.
- W3100613131 modified "2023-10-16" @default.
- W3100613131 title "Spectroscopic parameters and rest frequencies of isotopic methylidynium, CH<sup>+</sup>" @default.
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- W3100613131 doi "https://doi.org/10.1051/0004-6361/201014398" @default.
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