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- W3100613153 abstract "Abstract By using two organic raw materials 1,2-diphenyl-ethane-1,2-dione (ded) and benzene-1,2-diamine (bdm) under hydrothermal conditions, a Keggin-based compound modified by a big planar conjugated ligand was successfully synthesized, [Ag11Na3(L1)4(L2)2(H2O)4(H2PMo9VIMo3VO40)2] (1) (L1 = 1H-1,2,3,5,10-pentaaza-cylopenta[b]anthracene-4,11-dione, L2 = 6-nitro-1H-benzotriazole). The reactants ded and bdm convert into ligands L1 and L2 in situ by hydrothermal technique. Compound 1 shows a 3D framework with the 2D POM-based layers linked by Na and Ag5 atoms. In addition, the electrochemical and photocatalytic properties of this compound were also explored. Compound 1 can be used as a kind of POM-based electrocatalyst for the electrochemical reduction of CO2." @default.
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- W3100613153 date "2021-01-01" @default.
- W3100613153 modified "2023-09-23" @default.
- W3100613153 title "Synthesis, structure and properties of a three-dimensional polyoxometalate-based compound modified by two organic ligands" @default.
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- W3100613153 doi "https://doi.org/10.1016/j.inoche.2020.108338" @default.
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