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• W3100614246 abstract "The concept of modifying molecular dynamics in strongly coupled exciton-polariton systems is an emerging topic in photonics because of its potential to produce customized chemical systems with tailored photophysical properties. However, there is no consensus on the types of molecular systems whose dynamics can be modified using strong coupling or the conditions under which these modifications can be realized. These open questions stem from persistent uncertainties concerning the lifetime and conversion dynamics of exciton-polaritons and localized excited states, as well as the proper way to measure such interactions in the time domain. Here, we provide a framework for measuring dynamical interactions between exciton-polaritons and a diverse manifold of singlet, triplet, and multiexciton states, using a model molecular spin conversion (singlet fission) system that is strongly coupled to an optical microcavity. In addition to the usual population dynamics, transient optical measurements on microcavities reveal information pertaining to transient modifications of the exciton-polariton transition energies and exciton-photon coupling conditions. This approach allows to identify major practical limitations for modifying molecular dynamics in the strong coupling regime, including (1) absorption into the large number of “reservoir” states, defined as dark excitons (e.g., triplets) and the degenerate manifold of dark states from the collective strongly coupled molecules and all excitons from uncoupled molecules, compared to polariton states and (2) the slow conversion from reservoir states to cavity polaritons. As a consequence of weak interactions between reservoir states and cavity polaritons, judicious design considerations are required to achieve modified photophysical dynamics, necessitating the use of molecular systems with long excited-state lifetimes or architectures that enhance exciton-photon coupling strength such that a small number of molecules is required." @default.
• W3100614246 created "2020-11-23" @default.
• W3100614246 creator A5006992734 @default.
• W3100614246 creator A5010234675 @default.
• W3100614246 creator A5062833250 @default.
• W3100614246 date "2020-07-14" @default.
• W3100614246 modified "2023-10-06" @default.
• W3100614246 title "The Role of Long-Lived Excitons in the Dynamics of Strongly Coupled Molecular Polaritons" @default.
• W3100614246 cites W1489959446 @default.
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• W3100614246 cites W1930561965 @default.
• W3100614246 cites W1968758736 @default.
• W3100614246 cites W1978852531 @default.
• W3100614246 cites W1992620634 @default.
• W3100614246 cites W1999082732 @default.
• W3100614246 cites W2000842078 @default.
• W3100614246 cites W2005126509 @default.
• W3100614246 cites W2010056946 @default.
• W3100614246 cites W2018494532 @default.
• W3100614246 cites W2022997628 @default.
• W3100614246 cites W2027424192 @default.
• W3100614246 cites W2030828517 @default.
• W3100614246 cites W2032796094 @default.
• W3100614246 cites W2036722200 @default.
• W3100614246 cites W2037204247 @default.
• W3100614246 cites W2040235977 @default.
• W3100614246 cites W2047627799 @default.
• W3100614246 cites W2053491647 @default.
• W3100614246 cites W2053949848 @default.
• W3100614246 cites W2058242045 @default.
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• W3100614246 cites W2072164255 @default.
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• W3100614246 cites W2079636826 @default.
• W3100614246 cites W2081284721 @default.
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• W3100614246 cites W2321592239 @default.
• W3100614246 cites W2323333319 @default.
• W3100614246 cites W2324732748 @default.
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• W3100614246 cites W2409112513 @default.
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• W3100614246 cites W2533581290 @default.
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• W3100614246 cites W2743463626 @default.
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• W3100614246 doi "https://doi.org/10.1021/acsphotonics.0c00895" @default.
• W3100614246 hasPublicationYear "2020" @default.
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