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- W3100654808 abstract "Pressure-tuning spectroscopy is a powerful tool for investigating molecular interactions. These interactions may involve organic or inorganic materials in liquid, polymeric, or crystalline media. In this article we confine our attention to organic molecules, largely in dilute solution in polymers or liquids. We demonstrate the use of high-pressure luminescence to study the effect of the environment on π* →π, π* →n and charge-transfer excitations, as well as the interaction between singlet and triplet states. In addition, we provide tests of the energy gap law for non-radiative dissipation of excitation, the role of viscosity in luminescent efficiency, and the internal consistency of various means of predicting and correlating energy transfer. Over the past 40 years, it has been amply demonstrated that high pressure is a powerful tool for studying electronic phenomena in condensed phases. The basic concept is as follows. The optical, electrical, magnetic, and chemical properties—collectively the electronic properties—of condensed phases depend on the interactions of the outer electrons on the atoms, molecules, or ions that make up the phase. Different kinds of electronic orbitals have different spatial characteristics—different radial extent, different shape (orbital angular momentum), and different diffuseness; therefore, pressure perturbs the energies associated with these orbitals in different degrees. This relative perturbation we call “pressure tuning,” and the measurement and explanation of the tuning is “pressure-tuning spectroscopy.” Pressure-tuning spectroscopy of the vibrational and rotational excitations of atoms in molecular and in crystal lattices is also an active and important field, but in this article we arc concerned mainly with electronic phenomena. We further limit this discussion primarily to organic molecules in solid polymers or liquid solutions, as these have the greatest relevance to biologically active systems. A variety of probes are used for studying electronic phenomena under high pressure, but the emphasis here is on luminescence. The presentation consists of a series of examples of various types of excitations on interactions where high pressure has been an effective tool. Only references directly relevant to each example are included. Two general references to pressure studies of molecular luminescence have been published (Drickamer, 1982, 1990)." @default.
- W3100654808 created "2020-11-23" @default.
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- W3100654808 date "1996-10-10" @default.
- W3100654808 modified "2023-09-25" @default.
- W3100654808 title "Pressure-Tuning Spectroscopy: A Tool for Investigating Molecular Interactions" @default.
- W3100654808 doi "https://doi.org/10.1093/oso/9780195097221.003.0005" @default.
- W3100654808 hasPublicationYear "1996" @default.
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