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- W3100704712 abstract "Polarographic reduction of chromium (III) chloride hexahydrate (CrCl3⋅6H2O) has been studied in N, N-dimethylformamide (DMF) and dimethylsulfoxide (DMSO) containing 0.1M (C2H5)4 NCl as the supporting electrolyte. Chromium (III) chloride hexahydrate exhibited two reduction waves with wave height ratios of 1:2, and the limiting currents for these two reduction waves were diffusion controlled in the above solutions. In DMF, the first wave (the reciprocal slop of log-plot, large value) was irreversible, the second wave (the reciprocal slop: ca. 41mV) is reversible. In DMSO, the first wave (the reciprocal slop of log-plot: ca. 60mV), and the second wave (the reciprocal slop: ca. 36mV) are both reversible. In DMF, and DMSO, controlled potential coulometry at a potential on the plateau of the first, and the second waves showed an uptake of one electron, and three electrons per molecule, respectively. These facts suggest that the two reduction waves of chromium (III) chloride hexahydrate correspond to the reduction of Cr (III) to Cr (II) and Cr (0), respectively." @default.
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- W3100704712 doi "https://doi.org/10.4139/sfj1950.34.157" @default.
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