Matches in SemOpenAlex for { <https://semopenalex.org/work/W3100761685> ?p ?o ?g. }
- W3100761685 endingPage "125008" @default.
- W3100761685 startingPage "125008" @default.
- W3100761685 abstract "Recently synthesized Rh-Ni trinuclear complexes hexacoordinated with sulfur ions, 3-aminopropanethiolate (apt) metalloligand [Ni{Rh(apt)$_{3}$}$_{2}$](NO$_{3}$)$_{n}$ ($n$ = 2, 3, 4), are found to be chemically interconvertible between the nominal Ni$^{2+}$ and Ni$^{4+}$ states. In order to clarify the origins of their interconvertible nature and the stability of such a high oxidation state as the tetravalency from the physical point of view, we have systematically investigated the local 3$d$ electronic structures of [Ni{Rh(apt)$_{3}$}$_{2}$](NO$_{3}$)$_{n}$ by means of soft X-ray core-level absorption spectroscopy (XAS). The experimental data have been reproduced by the single-site configuration-interaction cluster-model simulations, which indicate that the charge-transferred configurations are more stable than the nominal $d$-electron-number configuration for $n=3,4$ leading to the prominent charge-transfer effects. These are also supported by S $K$-edge XAS of [Ni{Rh(apt)$_{3}$}$_{2}$](NO$_{3}$)$_{n}$. Our results imply that the found charge-transfer effects have a key role to realize the interconvertible nature as well as the stability of the high oxidization state of the Ni ions." @default.
- W3100761685 created "2020-11-23" @default.
- W3100761685 creator A5000133393 @default.
- W3100761685 creator A5012068288 @default.
- W3100761685 creator A5021610054 @default.
- W3100761685 creator A5054430046 @default.
- W3100761685 creator A5058302185 @default.
- W3100761685 creator A5077665509 @default.
- W3100761685 creator A5083628139 @default.
- W3100761685 creator A5090678127 @default.
- W3100761685 creator A5051605935 @default.
- W3100761685 date "2019-12-01" @default.
- W3100761685 modified "2023-09-27" @default.
- W3100761685 title "The prominent charge-transfer effects of trinuclear complexes with nominally high nickel valences" @default.
- W3100761685 cites W1508610974 @default.
- W3100761685 cites W1638019865 @default.
- W3100761685 cites W1641363979 @default.
- W3100761685 cites W1643423367 @default.
- W3100761685 cites W1679589259 @default.
- W3100761685 cites W1967660707 @default.
- W3100761685 cites W1969494873 @default.
- W3100761685 cites W1972439936 @default.
- W3100761685 cites W1975131266 @default.
- W3100761685 cites W1976994829 @default.
- W3100761685 cites W1999098063 @default.
- W3100761685 cites W1999974615 @default.
- W3100761685 cites W2013761935 @default.
- W3100761685 cites W2017764860 @default.
- W3100761685 cites W2022554164 @default.
- W3100761685 cites W2023563810 @default.
- W3100761685 cites W2027919131 @default.
- W3100761685 cites W2030798877 @default.
- W3100761685 cites W2032839511 @default.
- W3100761685 cites W2034141416 @default.
- W3100761685 cites W2040297785 @default.
- W3100761685 cites W2043078252 @default.
- W3100761685 cites W2044383845 @default.
- W3100761685 cites W2050315603 @default.
- W3100761685 cites W2054316210 @default.
- W3100761685 cites W2055545318 @default.
- W3100761685 cites W2062945373 @default.
- W3100761685 cites W2075966481 @default.
- W3100761685 cites W2079282312 @default.
- W3100761685 cites W2081912906 @default.
- W3100761685 cites W2087336484 @default.
- W3100761685 cites W2093162739 @default.
- W3100761685 cites W2103359505 @default.
- W3100761685 cites W2113883460 @default.
- W3100761685 cites W2129781958 @default.
- W3100761685 cites W2152206793 @default.
- W3100761685 cites W2155805802 @default.
- W3100761685 cites W2159476098 @default.
- W3100761685 cites W2164120424 @default.
- W3100761685 cites W2407637344 @default.
- W3100761685 cites W2573555028 @default.
- W3100761685 cites W2617775967 @default.
- W3100761685 cites W2747528682 @default.
- W3100761685 cites W2953007067 @default.
- W3100761685 cites W2965779348 @default.
- W3100761685 doi "https://doi.org/10.1088/2399-6528/ab5fab" @default.
- W3100761685 hasPublicationYear "2019" @default.
- W3100761685 type Work @default.
- W3100761685 sameAs 3100761685 @default.
- W3100761685 citedByCount "1" @default.
- W3100761685 countsByYear W31007616852022 @default.
- W3100761685 crossrefType "journal-article" @default.
- W3100761685 hasAuthorship W3100761685A5000133393 @default.
- W3100761685 hasAuthorship W3100761685A5012068288 @default.
- W3100761685 hasAuthorship W3100761685A5021610054 @default.
- W3100761685 hasAuthorship W3100761685A5051605935 @default.
- W3100761685 hasAuthorship W3100761685A5054430046 @default.
- W3100761685 hasAuthorship W3100761685A5058302185 @default.
- W3100761685 hasAuthorship W3100761685A5077665509 @default.
- W3100761685 hasAuthorship W3100761685A5083628139 @default.
- W3100761685 hasAuthorship W3100761685A5090678127 @default.
- W3100761685 hasBestOaLocation W31007616851 @default.
- W3100761685 hasConcept C119824511 @default.
- W3100761685 hasConcept C121332964 @default.
- W3100761685 hasConcept C123669783 @default.
- W3100761685 hasConcept C145148216 @default.
- W3100761685 hasConcept C147789679 @default.
- W3100761685 hasConcept C164866538 @default.
- W3100761685 hasConcept C178790620 @default.
- W3100761685 hasConcept C185592680 @default.
- W3100761685 hasConcept C188082385 @default.
- W3100761685 hasConcept C199360897 @default.
- W3100761685 hasConcept C2778591166 @default.
- W3100761685 hasConcept C41008148 @default.
- W3100761685 hasConcept C504270822 @default.
- W3100761685 hasConcept C518881349 @default.
- W3100761685 hasConcept C544153396 @default.
- W3100761685 hasConcept C62284982 @default.
- W3100761685 hasConcept C62520636 @default.
- W3100761685 hasConcept C8010536 @default.
- W3100761685 hasConceptScore W3100761685C119824511 @default.
- W3100761685 hasConceptScore W3100761685C121332964 @default.
- W3100761685 hasConceptScore W3100761685C123669783 @default.
- W3100761685 hasConceptScore W3100761685C145148216 @default.