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- W3100792944 abstract "Microgel suspensions of an interpenetrated Polymer Network (IPN) of PNIPAM and PAAc in D2O have been investigated through dynamic light scattering as a function of temperature, pH and concentration across the Volume Phase Transition (VPT). The dynamics of the system is slowed down under H/D isotopic substitution due to different balance states between polymer/polymer and polymer/solvent interactions suggesting the crucial role played by H-bonding. The swelling behavior, reduced with respect to PNIPAM and water, has been described by the Flory-Rehner theory, tested for PNIPAM microgel and successfully expanded to higher order for IPN microgels. Moreover the concentration dependence of the relaxation time at neutral pH has highlighted two different routes to approach the glass transition: Arrhenius and super-Arrhenius (Vogel Fulcher Tammann) respectively below and above the VPT and a fragility plot has been derived. Fragility can be tuned by changing temperature: across the VPT particles undergo a transition from soft-strong to stiff-fragile." @default.
- W3100792944 created "2020-11-23" @default.
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- W3100792944 creator A5052971984 @default.
- W3100792944 creator A5068755183 @default.
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- W3100792944 date "2017-01-01" @default.
- W3100792944 modified "2023-09-25" @default.
- W3100792944 title "Dynamical behavior of microgels of interpenetrated polymer networks" @default.
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- W3100792944 doi "https://doi.org/10.1039/c7sm00739f" @default.
- W3100792944 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28664963" @default.
- W3100792944 hasPublicationYear "2017" @default.
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