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• W3100824215 abstract "We performed a first principles investigation on the structural, electronic, and optical properties of crystals made of chemically functionalized adamantane molecules. Several molecular building blocks, formed by boron and nitrogen substitutional functionalizations, were considered to build zincblende and wurtzite crystals, and the resulting structures presented large bulk moduli and cohesive energies, wide and direct bandgaps, and low dielectric constants (low-$kappa$ materials). Those properties provide stability for such structures up to room temperature, superior to those of typical molecular crystals. This indicates a possible road map for crystal engineering using functionalized diamondoids, with potential applications ranging from space filling between conducting wires in nanodevices to nano-electro-mechanical systems." @default.
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• W3100824215 date "2010-07-16" @default.
• W3100824215 modified "2023-09-25" @default.
• W3100824215 title "Crystal engineering using functionalized adamantane" @default.
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• W3100824215 doi "https://doi.org/10.1088/0953-8984/22/31/315303" @default.
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