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- W3100829867 abstract "Using a unique home-made cell for four-contact impedance spectroscopy of conductive liquid samples, we establish the existence of two low frequency conductivity relaxations in aqueous solutions of gelatin, in both liquid and gel state. A comparison with diffusion measurements using pulsed field gradient NMR shows that the faster relaxation process is due to gelatin macromolecule self-diffusion. This single molecule diffusion is mostly insensitive to the macroscopic state of the sample, implying that the gelation of gelatin is not a percolative phenomenon, but is caused by aggregation of triple helices into a system-spanning fibre network." @default.
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- W3100829867 date "2014-01-01" @default.
- W3100829867 modified "2023-10-01" @default.
- W3100829867 title "Role of microscopic phase separation in gelation of aqueous gelatin solutions" @default.
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- W3100829867 doi "https://doi.org/10.1039/c3sm52542b" @default.
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