Matches in SemOpenAlex for { <https://semopenalex.org/work/W3100848433> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W3100848433 abstract "Coulomb repulsion between the bonding electron pair in the H-O covalent bond (denoted by -) and the nonbonding electron pair of O (:) and the specific-heat disparity between the O:H and the H-O segments of the entire hydrogen bond (O:H-O) are shown to determine the O:H-O bond angle-length-stiffness relaxation dynamics and the density anomalies of water and ice. The bonding part with relatively lower specific-heat is more easily activated by cooling, which serves as the and contracts, while forcing the with higher specific-heat to elongate (via Coulomb repulsion) by different amounts. In the liquid and solid phases, the O:H van der Waals bond serves as the master and becomes significantly shorter and stiffer while the H-O bond becomes slightly longer and softer (phonon frequency is a measure of bond stiffness), resulting in an O:H-O cooling contraction and the seemingly regular process of cooling densification. In the water-ice transition phase, the master and the slave swap roles, thus resulting in an O:H-O elongation and volume expansion during freezing. In ice, the O--O distance is longer than it is in water, resulting in a lower density, so that ice floats." @default.
- W3100848433 created "2020-11-23" @default.
- W3100848433 creator A5087389582 @default.
- W3100848433 date "2012-10-05" @default.
- W3100848433 modified "2023-09-27" @default.
- W3100848433 title "Mass-density and Phonon-frequency Relaxation Dynamics of Water and Ice at Cooling" @default.
- W3100848433 cites W1978066323 @default.
- W3100848433 cites W2000196463 @default.
- W3100848433 cites W2033128041 @default.
- W3100848433 cites W2043335768 @default.
- W3100848433 cites W2049603070 @default.
- W3100848433 cites W2061174842 @default.
- W3100848433 cites W2061741766 @default.
- W3100848433 cites W2062276774 @default.
- W3100848433 cites W2091654157 @default.
- W3100848433 cites W2114131956 @default.
- W3100848433 cites W2122422038 @default.
- W3100848433 cites W2137352412 @default.
- W3100848433 cites W2139511716 @default.
- W3100848433 cites W2140531910 @default.
- W3100848433 cites W2146462263 @default.
- W3100848433 cites W2163440447 @default.
- W3100848433 cites W2318780475 @default.
- W3100848433 cites W2328340213 @default.
- W3100848433 cites W2328807407 @default.
- W3100848433 hasPublicationYear "2012" @default.
- W3100848433 type Work @default.
- W3100848433 sameAs 3100848433 @default.
- W3100848433 citedByCount "5" @default.
- W3100848433 countsByYear W31008484332013 @default.
- W3100848433 countsByYear W31008484332017 @default.
- W3100848433 countsByYear W31008484332019 @default.
- W3100848433 crossrefType "journal-article" @default.
- W3100848433 hasAuthorship W3100848433A5087389582 @default.
- W3100848433 hasBestOaLocation W31008484331 @default.
- W3100848433 hasConcept C112887158 @default.
- W3100848433 hasConcept C121332964 @default.
- W3100848433 hasConcept C125485243 @default.
- W3100848433 hasConcept C126061179 @default.
- W3100848433 hasConcept C147120987 @default.
- W3100848433 hasConcept C178790620 @default.
- W3100848433 hasConcept C180577832 @default.
- W3100848433 hasConcept C185592680 @default.
- W3100848433 hasConcept C192562407 @default.
- W3100848433 hasConcept C24169881 @default.
- W3100848433 hasConcept C26873012 @default.
- W3100848433 hasConcept C2779529193 @default.
- W3100848433 hasConcept C32909587 @default.
- W3100848433 hasConcept C62520636 @default.
- W3100848433 hasConcept C8010536 @default.
- W3100848433 hasConcept C9342510 @default.
- W3100848433 hasConcept C97355855 @default.
- W3100848433 hasConceptScore W3100848433C112887158 @default.
- W3100848433 hasConceptScore W3100848433C121332964 @default.
- W3100848433 hasConceptScore W3100848433C125485243 @default.
- W3100848433 hasConceptScore W3100848433C126061179 @default.
- W3100848433 hasConceptScore W3100848433C147120987 @default.
- W3100848433 hasConceptScore W3100848433C178790620 @default.
- W3100848433 hasConceptScore W3100848433C180577832 @default.
- W3100848433 hasConceptScore W3100848433C185592680 @default.
- W3100848433 hasConceptScore W3100848433C192562407 @default.
- W3100848433 hasConceptScore W3100848433C24169881 @default.
- W3100848433 hasConceptScore W3100848433C26873012 @default.
- W3100848433 hasConceptScore W3100848433C2779529193 @default.
- W3100848433 hasConceptScore W3100848433C32909587 @default.
- W3100848433 hasConceptScore W3100848433C62520636 @default.
- W3100848433 hasConceptScore W3100848433C8010536 @default.
- W3100848433 hasConceptScore W3100848433C9342510 @default.
- W3100848433 hasConceptScore W3100848433C97355855 @default.
- W3100848433 hasLocation W31008484331 @default.
- W3100848433 hasLocation W31008484332 @default.
- W3100848433 hasOpenAccess W3100848433 @default.
- W3100848433 hasPrimaryLocation W31008484331 @default.
- W3100848433 hasRelatedWork W1511129382 @default.
- W3100848433 hasRelatedWork W1564681792 @default.
- W3100848433 hasRelatedWork W1743791033 @default.
- W3100848433 hasRelatedWork W1993869400 @default.
- W3100848433 hasRelatedWork W1996854030 @default.
- W3100848433 hasRelatedWork W1999251332 @default.
- W3100848433 hasRelatedWork W2011619853 @default.
- W3100848433 hasRelatedWork W2017297771 @default.
- W3100848433 hasRelatedWork W2040277608 @default.
- W3100848433 hasRelatedWork W2049603070 @default.
- W3100848433 hasRelatedWork W2066053102 @default.
- W3100848433 hasRelatedWork W2122422038 @default.
- W3100848433 hasRelatedWork W2128569052 @default.
- W3100848433 hasRelatedWork W2133431683 @default.
- W3100848433 hasRelatedWork W2258122355 @default.
- W3100848433 hasRelatedWork W2298832176 @default.
- W3100848433 hasRelatedWork W2490467510 @default.
- W3100848433 hasRelatedWork W3099980374 @default.
- W3100848433 hasRelatedWork W3102363772 @default.
- W3100848433 isParatext "false" @default.
- W3100848433 isRetracted "false" @default.
- W3100848433 magId "3100848433" @default.
- W3100848433 workType "article" @default.