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- W3100877118 abstract "Haloacetamides (HAcAms) is ubiquitously found in drinking water, which exhibits strong cytotoxicity and genotoxicity compared with conventional disinfection byproducts (DBPs). Herein, the degradation of HAcAms containing dichloroacetamide (DCAcAm) and trichloroacetamide (TCAcAm) by UV/peroxymonosulfate (PMS) process was studied. Degradation kinetics of DCAcAm and TCAcAm conformed to the first-order model, and the corresponding reaction constants were 2.27 × 10−3 and 1.94 × 10−3 s−1, respectively. The degradation rate raised with the increment of PMS dosage. During the investigation of water matrices including Cl–, HCO3–, and humic acid (HA), HCO3– and HA inhibited the degradation process whereas the influence of Cl– on the degradation was negligible. As evidenced by trapping test, •OH played the crucial role in the degradation of HAcAms. During the UV/PMS process, dechlorination was the main process. TCAcAm could be oxidized to DCAcAm and acetamide, and further mineralized to Cl–, CO2, H2O, NO2–, and NO3–. Our results demonstrated that UV/PMS could be an effective technique to degrade HAcAms in dinking water." @default.
- W3100877118 created "2020-11-23" @default.
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- W3100877118 date "2020-11-08" @default.
- W3100877118 modified "2023-10-14" @default.
- W3100877118 title "UV-activated peroxymonosulfate for haloacetamides degradation: Kinetics and reaction pathways" @default.
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- W3100877118 doi "https://doi.org/10.1080/01932691.2020.1842756" @default.
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