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• W3100907654 abstract "We use a network of molecularly linked gold nanoparticles (NPSAN: nanoparticles self-assembled network) to demonstrate the electrical detection (conductance variation) of a plasmon-induced isomerization (PII) of azobenzene derivatives (azobenzene bithiophene : AzBT). We show that PII is more efficient in a 3D-like (cluster-NPSAN) than in a purely two-dimensional NPSAN (i.e., a monolayer of AzBT functionalized Au NPs). By comparison with usual optical (UV-visible light) isomerization of AzBT, the PII shows a faster (a factor about 10) isomerization kinetics. Possible PII mechanisms are discussed: electric field-induced isomerization, two-phonon process, plasmon-induced resonant energy transfer (PIRET), the latter being the most likely." @default.
• W3100907654 created "2020-11-23" @default.
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• W3100907654 date "2018-01-01" @default.
• W3100907654 modified "2023-10-17" @default.
• W3100907654 title "Electrical detection of plasmon-induced isomerization in molecule–nanoparticle network devices" @default.
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• W3100907654 doi "https://doi.org/10.1039/c8nr07603k" @default.
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