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• W3100984105 startingPage "9086" @default.
• W3100984105 abstract "A general, convenient, and friendly route for preparing a versatile building block of isocyanides from primary amines is developed. Difluorocarbene, generated in situ from decarboxylation of chlorodifluoroacetate, reacts efficiently with primary amines to produce isocyanides. Various primary amines are well tolerated, including aryl, heteroaryl, benzyl, and alkyl amines, as well as amine residues in amino acids and peptides. Late-stage functionalization of biologically active amines is demonstrated, showing its practical capacity in drug design and peptide modification." @default.
• W3100984105 created "2020-11-23" @default.
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• W3100984105 date "2020-11-09" @default.
• W3100984105 modified "2023-10-17" @default.
• W3100984105 title "Synthesis of Isocyanides by Reacting Primary Amines with Difluorocarbene" @default.
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• W3100984105 doi "https://doi.org/10.1021/acs.orglett.0c03472" @default.
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