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- W3100996467 abstract "Theory of superexchange interaction between $J$-multiplets in $f$ metal compounds is developed for an adequate description of Goodenough mechanism induced by the electron transfer between the magnetic $f$ orbitals and empty $d$ and $s$ orbitals. The developed multipolar exchange model is applied to ferromagnetic NdN by using first principles microscopic parameters. The multipolar interaction parameters up to nineth order are quantitatively determined, and the significance of the higher order interaction is confirmed. The basic magnetic properties such as magnetization and magnetic susceptibility of NdN are well reproduced with the model. In the calculated ferromagnetic phase, it is shown that the quadrupole and octupole moments develop (within ground $Gamma_8$ multiplets), unambiguously indicating the significance of the multipolar interactions." @default.
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- W3100996467 date "2020-11-19" @default.
- W3100996467 modified "2023-09-27" @default.
- W3100996467 title "First principles theory of multipolar interaction in ferromagnetic rare-earth nitride" @default.
- W3100996467 hasPublicationYear "2020" @default.
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