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- W3101284899 abstract "Herein, we report the synthesis of a series of bis(silanechalcogenones) [Ch = Te (2), S (3), or Se (4)] using an N-heterocyclic silylene-based SiCSi pincer ligand (1). 2 is the first example of a bis(silanetellurone) derivative. The bonding patterns of 2-4 were extensively studied by natural bond orbital, quantum theory of atoms in molecules, and noncovalent interaction index analyses, and these exhibit weak C-H···Ch interaction. The analogous reaction of 1 with trimethyl N-oxide produced a novel bis(cyclosiloxane) derivative (5). All of the complexes are duly characterized by single-crystal X-ray diffraction studies, multinuclear nuclear magnetic resonance (1H, 13C, and 29Si) spectroscopy, and high-resolution mass spectrometry." @default.
- W3101284899 created "2020-11-23" @default.
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- W3101284899 date "2020-11-20" @default.
- W3101284899 modified "2023-09-26" @default.
- W3101284899 title "Bis(silanetellurone) with C–H···Te Interaction" @default.
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- W3101284899 doi "https://doi.org/10.1021/acs.inorgchem.0c03098" @default.
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