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• W3102869276 abstract "Abstract We demonstrate the microscopic role of oxygen vacancies spatially confined within nanometer inter-spacing (about 1 nm) in BiFeO 3 , using resonant soft X-ray scattering techniques and soft X-ray spectroscopy measurements. Such vacancy confinements and total number of vacancy are controlled by substitution of Ca 2+ for Bi 3+ cation. We found that by increasing the substitution, the in-plane orbital bands of Fe 3+ cations are reconstructed without any redox reaction. It leads to a reduction of the hopping between Fe atoms, forming a localized valence band, in particular Fe 3 d -electronic structure, around the Fermi level. This band localization causes to decrease the conductivity of the doped BiFeO 3 system." @default.
• W3102869276 created "2020-11-23" @default.
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• W3102869276 date "2015-07-27" @default.
• W3102869276 modified "2023-10-18" @default.
• W3102869276 title "Orbital Reconstruction in a Self-assembled Oxygen Vacancy Nanostructure" @default.
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• W3102869276 doi "https://doi.org/10.1038/srep12402" @default.
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• W3102869276 hasPublicationYear "2015" @default.
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