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- W3103095900 abstract "Abstract A combined experimental and theoretical approach has been used to investigate X − ⋅⋅⋅CH 2 O (X=F, Cl, Br, I) complexes in the gas phase. Photoelectron spectroscopy, in tandem with time‐of‐flight mass spectrometry, has been used to determine electron binding energies for the Cl − ⋅⋅⋅CH 2 O, Br − ⋅⋅⋅CH 2 O, and I − ⋅⋅⋅CH 2 O species. Additionally, high‐level CCSD(T) calculations found a C 2v minimum for these three anion complexes, with predicted electron detachment energies in excellent agreement with the experimental photoelectron spectra. F − ⋅⋅⋅CH 2 O was also studied theoretically, with a C s hydrogen‐bonded complex found to be the global minimum. Calculations extended to neutral X⋅⋅⋅CH 2 O complexes, with the results of potential interest to atmospheric CH 2 O chemistry." @default.
- W3103095900 created "2020-11-23" @default.
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- W3103095900 date "2020-12-01" @default.
- W3103095900 modified "2023-10-03" @default.
- W3103095900 title "Photoelectron Spectroscopy and Structures of X <sup>−</sup> ⋅⋅⋅CH <sub>2</sub> O (X=F, Cl, Br, I) Complexes" @default.
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- W3103095900 doi "https://doi.org/10.1002/cphc.202000852" @default.
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