FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3103181867> ?p ?o ?g. }

• W3103181867 endingPage "034002" @default.
• W3103181867 startingPage "034002" @default.
• W3103181867 abstract "Solar thermal fuels (STFs) are an unconventional paradigm for solar energy conversion and storage which is attracting renewed attention. In this concept, a material absorbs sunlight and stores the energy chemically via an induced structural change, which can later be reversed to release the energy as heat. An example is the azobenzene molecule which has a cis-trans photoisomerization with these properties, and can be tuned by chemical substitution and attachment to templates such as carbon nanotubes, small molecules, or polymers. By analogy to the Shockley-Queisser limit for photovoltaics, we analyze the maximum attainable efficiency for STFs from fundamental thermodynamic considerations. Microscopic reversibility provides a bound on the quantum yield of photoisomerization due to fluorescence, regardless of details of photochemistry. We emphasize the importance of analyzing the free energy, not just enthalpy, of the metastable molecules, and find an efficiency limit for conversion to stored chemical energy equal to the Shockley-Queisser limit. STF candidates from a recent high-throughput search are analyzed in light of the efficiency limit." @default.
• W3103181867 created "2020-11-23" @default.
• W3103181867 creator A5075873771 @default.
• W3103181867 creator A5083309623 @default.
• W3103181867 date "2018-12-07" @default.
• W3103181867 modified "2023-09-30" @default.
• W3103181867 title "Thermodynamic limits to energy conversion in solar thermal fuels" @default.
• W3103181867 cites W1770664584 @default.
• W3103181867 cites W1982935712 @default.
• W3103181867 cites W1984727064 @default.
• W3103181867 cites W1987347836 @default.
• W3103181867 cites W1996782241 @default.
• W3103181867 cites W2026116093 @default.
• W3103181867 cites W2029637177 @default.
• W3103181867 cites W2037221035 @default.
• W3103181867 cites W2040432535 @default.
• W3103181867 cites W2046130208 @default.
• W3103181867 cites W2048591531 @default.
• W3103181867 cites W2053858888 @default.
• W3103181867 cites W2056721644 @default.
• W3103181867 cites W2084856161 @default.
• W3103181867 cites W2085201181 @default.
• W3103181867 cites W2092891366 @default.
• W3103181867 cites W2099200340 @default.
• W3103181867 cites W2099415222 @default.
• W3103181867 cites W2137249141 @default.
• W3103181867 cites W2153986480 @default.
• W3103181867 cites W2160142118 @default.
• W3103181867 cites W2169839000 @default.
• W3103181867 cites W2210107001 @default.
• W3103181867 cites W2335669350 @default.
• W3103181867 cites W2416150540 @default.
• W3103181867 cites W2490995317 @default.
• W3103181867 cites W2519530436 @default.
• W3103181867 cites W2553487320 @default.
• W3103181867 cites W2754822816 @default.
• W3103181867 cites W3208796882 @default.
• W3103181867 doi "https://doi.org/10.1088/1361-648x/aaef5a" @default.
• W3103181867 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30523877" @default.
• W3103181867 hasPublicationYear "2018" @default.
• W3103181867 type Work @default.
• W3103181867 sameAs 3103181867 @default.
• W3103181867 citedByCount "10" @default.
• W3103181867 countsByYear W31031818672019 @default.
• W3103181867 countsByYear W31031818672020 @default.
• W3103181867 countsByYear W31031818672021 @default.
• W3103181867 countsByYear W31031818672022 @default.
• W3103181867 countsByYear W31031818672023 @default.
• W3103181867 crossrefType "journal-article" @default.
• W3103181867 hasAuthorship W3103181867A5075873771 @default.
• W3103181867 hasAuthorship W3103181867A5083309623 @default.
• W3103181867 hasBestOaLocation W31031818672 @default.
• W3103181867 hasConcept C107861326 @default.
• W3103181867 hasConcept C120665830 @default.
• W3103181867 hasConcept C121332964 @default.
• W3103181867 hasConcept C126661725 @default.
• W3103181867 hasConcept C144822601 @default.
• W3103181867 hasConcept C159467904 @default.
• W3103181867 hasConcept C161790260 @default.
• W3103181867 hasConcept C171001562 @default.
• W3103181867 hasConcept C178790620 @default.
• W3103181867 hasConcept C183287310 @default.
• W3103181867 hasConcept C185592680 @default.
• W3103181867 hasConcept C18903297 @default.
• W3103181867 hasConcept C192562407 @default.
• W3103181867 hasConcept C204530211 @default.
• W3103181867 hasConcept C205507967 @default.
• W3103181867 hasConcept C206991015 @default.
• W3103181867 hasConcept C22547674 @default.
• W3103181867 hasConcept C2778150588 @default.
• W3103181867 hasConcept C32909587 @default.
• W3103181867 hasConcept C41291067 @default.
• W3103181867 hasConcept C49040817 @default.
• W3103181867 hasConcept C541104983 @default.
• W3103181867 hasConcept C542589376 @default.
• W3103181867 hasConcept C85311670 @default.
• W3103181867 hasConcept C86803240 @default.
• W3103181867 hasConcept C89464430 @default.
• W3103181867 hasConcept C91881484 @default.
• W3103181867 hasConcept C97355855 @default.
• W3103181867 hasConceptScore W3103181867C107861326 @default.
• W3103181867 hasConceptScore W3103181867C120665830 @default.
• W3103181867 hasConceptScore W3103181867C121332964 @default.
• W3103181867 hasConceptScore W3103181867C126661725 @default.
• W3103181867 hasConceptScore W3103181867C144822601 @default.
• W3103181867 hasConceptScore W3103181867C159467904 @default.
• W3103181867 hasConceptScore W3103181867C161790260 @default.
• W3103181867 hasConceptScore W3103181867C171001562 @default.
• W3103181867 hasConceptScore W3103181867C178790620 @default.
• W3103181867 hasConceptScore W3103181867C183287310 @default.
• W3103181867 hasConceptScore W3103181867C185592680 @default.
• W3103181867 hasConceptScore W3103181867C18903297 @default.
• W3103181867 hasConceptScore W3103181867C192562407 @default.
• W3103181867 hasConceptScore W3103181867C204530211 @default.
• W3103181867 hasConceptScore W3103181867C205507967 @default.
• W3103181867 hasConceptScore W3103181867C206991015 @default.
• W3103181867 hasConceptScore W3103181867C22547674 @default.
• W3103181867 hasConceptScore W3103181867C2778150588 @default.

• next