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• W3103307389 abstract "Abstract Permanganyl fluoride's existence at the stability threshold in the series of oxides and oxide fluorides of the late 3d transition metals is reflected by its experimentally challenging properties and by the difficulties posed in the theoretical description of its bonding characteristics. The history of this molecule is reviewed from early qualitative observations and the growing scattered information on its chemical and physical properties to the accurate determination and interpretation of its molecular structure and spectral features. The still problematic theoretical models for MnO 4 − and MnO 3 F are briefly presented in the broader context of the chemistry of elements in high oxidation states. Short biographies of the scientists engaged in these studies are offered. Related technetium and rhenium compounds are briefly considered for comparison." @default.
• W3103307389 created "2020-11-23" @default.
• W3103307389 creator A5009697850 @default.
• W3103307389 creator A5036764619 @default.
• W3103307389 date "2021-02-24" @default.
• W3103307389 modified "2023-09-23" @default.
• W3103307389 title "Permanganyl Fluoride: A Brief History of the Molecule MnO ₃ F and of Those Who Cared For It" @default.
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• W3103307389 doi "https://doi.org/10.1002/chem.202004759" @default.
• W3103307389 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8247864" @default.
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