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• W3103525620 abstract "The fluctuations of optical gap induced by the environment play crucial roles in electronic energy transfer dynamics. One of the simplest approaches to incorporate such fluctuations in energy transfer dynamics is the well known Haken-Strobl-Reineker model, in which the energy-gap fluctuation is approximated as a white noise. Recently, several groups have employed molecular dynamics simulations and excited-state calculations in conjunction to take the thermal fluctuation of excitation energies into account. Here, we discuss a rigorous connection between the stochastic and the atomistic bath models. If the phonon bath is treated classically, time evolution of the exciton-phonon system can be described by Ehrenfest dynamics. To establish the relationship between the stochastic and atomistic bath models, we employ a projection operator technique to derive the generalized Langevin equations for the energy-gap fluctuations. The stochastic bath model can be obtained as an approximation of the atomistic Ehrenfest equations via the generalized Langevin approach. Based on the connection, we propose a novel scheme to correct reorganization effects within the framework of stochastic models. The proposed scheme provides a better description of the population dynamics especially in the regime of strong exciton-phonon coupling. Finally, we discuss the effect of the bath reorganization in the absorption and fluorescence spectra of ideal J-aggregates in terms of the Stokes shifts. For this purpose, we introduce a simple relationship that relates the reorganization contribution to the Stokes shifts - the reorganization shift - to three parameters: the monomer reorganization energy, the relaxation time of the optical gap, and the exciton delocalization length. This simple relationship allows one to classify the origin of the Stokes shifts in molecular aggregates." @default.
• W3103525620 created "2020-11-23" @default.
• W3103525620 creator A5071495561 @default.
• W3103525620 creator A5074343703 @default.
• W3103525620 creator A5083687252 @default.
• W3103525620 date "2014-06-23" @default.
• W3103525620 modified "2023-10-03" @default.
• W3103525620 title "A stochastic reorganizational bath model for electronic energy transfer" @default.
• W3103525620 cites W1517529256 @default.
• W3103525620 cites W1964670349 @default.
• W3103525620 cites W1971857158 @default.
• W3103525620 cites W1973259535 @default.
• W3103525620 cites W1974453056 @default.
• W3103525620 cites W1976265907 @default.
• W3103525620 cites W1976269136 @default.
• W3103525620 cites W1978670093 @default.
• W3103525620 cites W1981387309 @default.
• W3103525620 cites W1981417082 @default.
• W3103525620 cites W1981520015 @default.
• W3103525620 cites W1982574512 @default.
• W3103525620 cites W1982972906 @default.
• W3103525620 cites W1984775475 @default.
• W3103525620 cites W1991498668 @default.
• W3103525620 cites W1993739693 @default.
• W3103525620 cites W2002742052 @default.
• W3103525620 cites W2007556342 @default.
• W3103525620 cites W2013398650 @default.
• W3103525620 cites W2018763953 @default.
• W3103525620 cites W2020347728 @default.
• W3103525620 cites W2021416051 @default.
• W3103525620 cites W2021880807 @default.
• W3103525620 cites W2024067209 @default.
• W3103525620 cites W2025218022 @default.
• W3103525620 cites W2026766829 @default.
• W3103525620 cites W2030104505 @default.
• W3103525620 cites W2037228601 @default.
• W3103525620 cites W2037419497 @default.
• W3103525620 cites W2040171281 @default.
• W3103525620 cites W2048385187 @default.
• W3103525620 cites W2048860988 @default.
• W3103525620 cites W2053839673 @default.
• W3103525620 cites W2055032509 @default.
• W3103525620 cites W2056127610 @default.
• W3103525620 cites W2056896873 @default.
• W3103525620 cites W2058468006 @default.
• W3103525620 cites W2063212260 @default.
• W3103525620 cites W2064799975 @default.
• W3103525620 cites W2066245794 @default.
• W3103525620 cites W2067889970 @default.
• W3103525620 cites W2068406897 @default.
• W3103525620 cites W2069688935 @default.
• W3103525620 cites W2072350015 @default.
• W3103525620 cites W2077841486 @default.
• W3103525620 cites W2078142786 @default.
• W3103525620 cites W2078679157 @default.
• W3103525620 cites W2080879353 @default.
• W3103525620 cites W2082479893 @default.
• W3103525620 cites W2084333107 @default.
• W3103525620 cites W2088136500 @default.
• W3103525620 cites W2090062662 @default.
• W3103525620 cites W2090106994 @default.
• W3103525620 cites W2090620271 @default.
• W3103525620 cites W2102080148 @default.
• W3103525620 cites W2102296190 @default.
• W3103525620 cites W2113263193 @default.
• W3103525620 cites W2118881986 @default.
• W3103525620 cites W2124138287 @default.
• W3103525620 cites W2127296814 @default.
• W3103525620 cites W2137948858 @default.
• W3103525620 cites W2143423258 @default.
• W3103525620 cites W2149791925 @default.
• W3103525620 cites W2150852355 @default.
• W3103525620 cites W2152647108 @default.
• W3103525620 cites W2154338418 @default.
• W3103525620 cites W2157122290 @default.
• W3103525620 cites W2158777069 @default.
• W3103525620 cites W2167373328 @default.
• W3103525620 cites W2318490369 @default.
• W3103525620 cites W2326506907 @default.
• W3103525620 cites W2746718465 @default.
• W3103525620 cites W3099302868 @default.
• W3103525620 cites W3099765863 @default.
• W3103525620 cites W3100641251 @default.
• W3103525620 cites W3101071278 @default.
• W3103525620 cites W3101787887 @default.
• W3103525620 cites W3102368044 @default.
• W3103525620 cites W3102549676 @default.
• W3103525620 cites W3103399702 @default.
• W3103525620 cites W3105874551 @default.
• W3103525620 cites W3106097037 @default.
• W3103525620 cites W4231206741 @default.
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• W3103525620 doi "https://doi.org/10.1063/1.4883862" @default.
• W3103525620 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24985614" @default.
• W3103525620 hasPublicationYear "2014" @default.
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