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• W3103900264 abstract "We study crystallization in a model system for eicosane (C20) by means of molecular dynamics simulation and identify the microscopic mechanisms of homogeneous crystal nucleation and growth. For the nucleation process, we observe that chains first align and then straighten. Then the local density increases and finally the monomer units become ordered positionally. The subsequent crystal growth process is characterized by a sliding-in motion of the chains. Chains preferably attach to the crystalline cluster with one end and then move along the stems of already crystallized chains towards their final position. This process is cooperative, i.e., neighboring chains tend to get attached in clusters rather than independently." @default.
• W3103900264 created "2020-11-23" @default.
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• W3103900264 creator A5051784439 @default.
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• W3103900264 date "2013-12-04" @default.
• W3103900264 modified "2023-09-25" @default.
• W3103900264 title "Crystallization mechanism in melts of short n-alkane chains" @default.
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• W3103900264 doi "https://doi.org/10.1063/1.4835015" @default.
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