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• W3104003428 abstract "In the present article we carry out a molecular dynamics study of the core-softened system and show that the existence of the water-like anomalies in this system depends on the trajectory in P–ρ–T space along which the behavior of the system is studied. For example, diffusion and structural anomalies are visible along isotherms as a function of density, but disappears along the isochores and isobars as a function of temperature. On the other hand, the diffusion anomaly may be seen along adiabats as a function of temperature, density, and pressure. It should be noted that it may be no signature of a particular anomaly along a particular trajectory, but the anomalous region for that particular anomaly can be defined when all possible trajectories in the same space are examined (for example, signature of diffusion anomaly is evident through the crossing of different isochors. However, there is no signature of diffusion anomaly along a particular isochor). We also analyze the applicability of the Rosenfeld entropy scaling relations to this system in the regions with the water-like anomalies. It is shown that the validity of the Rosenfeld scaling relation for the diffusion coefficient also depends on the trajectory in the P–ρ–T space along which the kinetic coefficients and the excess entropy are calculated." @default.
• W3104003428 created "2020-11-23" @default.
• W3104003428 creator A5018771135 @default.
• W3104003428 creator A5047658478 @default.
• W3104003428 creator A5071674339 @default.
• W3104003428 date "2011-09-28" @default.
• W3104003428 modified "2023-09-23" @default.
• W3104003428 title "Core-softened system with attraction: Trajectory dependence of anomalous behavior" @default.
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• W3104003428 doi "https://doi.org/10.1063/1.3643115" @default.
• W3104003428 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21974540" @default.
• W3104003428 hasPublicationYear "2011" @default.
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