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- W3104254883 abstract "Abstract The activation of strong C–O bonds in cross-coupling catalysis can open up new oxygenate-based feedstocks and building blocks for complex-molecule synthesis. Although Ni catalysis has been the major focus for cross-coupling of carboxylate-based electrophiles, we recently demonstrated that palladium catalyzes not only difficult C–O oxidative additions but also Suzuki-type cross-couplings of alkenyl carboxylates under mild conditions. We propose that, depending on the reaction conditions, either a typical Pd(0)/(II) mechanism or a redox-neutral Pd(II)-only mechanism can operate. In the latter pathway, C–C bond formation occurs through carbopalladation of the alkene, and C–O cleavage by β-carboxyl elimination. 1 Introduction 2 A Mechanistic Challenge: Activating Strong C–O Bonds 3 Exploiting Vinylogy for C–Cl and C–O Oxidative Additions 4 An Alternative Mechanism for Efficient Cross-Coupling Catalysis 5 Conclusions and Outlook" @default.
- W3104254883 created "2020-11-23" @default.
- W3104254883 creator A5025154329 @default.
- W3104254883 creator A5041333769 @default.
- W3104254883 date "2020-11-09" @default.
- W3104254883 modified "2023-10-18" @default.
- W3104254883 title "C–O Bond Activation as a Strategy in Palladium-Catalyzed Cross-Coupling" @default.
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- W3104254883 doi "https://doi.org/10.1055/a-1306-3228" @default.
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