FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3104789637> ?p ?o ?g. }

• W3104789637 abstract "Atomistic simulations have been performed to investigate the effect of aliphatic chain length in tetraalkylphosphonium cations on liquid morphologies, microscopic ionic structures and dynamical properties of tetraalkylphosphonium chloride ionic liquids. The liquid morphologies are characterized by sponge-like interpenetrating polar and apolar networks in ionic liquids consisting of tetraalkylphosphonium cations with short aliphatic chains. The lengthening aliphatic chains in tetraalkylphosphonium cations leads to polar domains consisting of chloride anions and central polar groups in cations being partially or totally segregated in ionic liquid matrices due to a progressive expansion of apolar domains in between. Prominent polarity alternation peaks and adjacency correlation peaks are observed at low and high $q$ range in total X-ray scattering structural functions, respectively, and their peak positions gradually shift to lower q values with lengthening aliphatic chains in tetraalkylphosphonium cations. The charge alternation peaks registered in intermediate q range exhibit complicated tendencies due to the complete cancellations of peaks and anti-peaks in partial structural functions for ionic subcomponents. The particular microstructures and liquid morphologies in tetraalkylphosphonium chloride ionic liquids intrinsically contribute to distinct dynamics characterized by translational diffusion coefficients, van Hove correlation functions, and non-Gaussian parameters for ionic species in heterogeneous ionic environment. The increase of aliphatic chain length in tetraalkylphosphonium cations leads to concomitant shift of van Hove correlation functions and non-Gaussian parameters to larger radial distances and longer timescales, respectively, indicating the enhanced translational dynamical heterogeneities of tetraalkylphosphonium cations and the corresponding chloride anions." @default.
• W3104789637 created "2020-11-23" @default.
• W3104789637 creator A5016635939 @default.
• W3104789637 creator A5030943980 @default.
• W3104789637 creator A5080723157 @default.
• W3104789637 creator A5087678650 @default.
• W3104789637 date "2017-12-08" @default.
• W3104789637 modified "2023-10-17" @default.
• W3104789637 title "Microstructures and dynamics of tetraalkylphosphonium chloride ionic liquids" @default.
• W3104789637 cites W1600292521 @default.
• W3104789637 cites W1919995897 @default.
• W3104789637 cites W1963932165 @default.
• W3104789637 cites W1965200916 @default.
• W3104789637 cites W1966078827 @default.
• W3104789637 cites W1970419395 @default.
• W3104789637 cites W1973008529 @default.
• W3104789637 cites W1976496891 @default.
• W3104789637 cites W1980616812 @default.
• W3104789637 cites W1982479518 @default.
• W3104789637 cites W1984699819 @default.
• W3104789637 cites W1988048427 @default.
• W3104789637 cites W1993532374 @default.
• W3104789637 cites W1995863104 @default.
• W3104789637 cites W1997724015 @default.
• W3104789637 cites W2001444533 @default.
• W3104789637 cites W2002530725 @default.
• W3104789637 cites W2002963311 @default.
• W3104789637 cites W2005307077 @default.
• W3104789637 cites W2005860814 @default.
• W3104789637 cites W2011149424 @default.
• W3104789637 cites W2013478319 @default.
• W3104789637 cites W2013558661 @default.
• W3104789637 cites W2014919752 @default.
• W3104789637 cites W2017747065 @default.
• W3104789637 cites W2022875681 @default.
• W3104789637 cites W2040521334 @default.
• W3104789637 cites W2044089975 @default.
• W3104789637 cites W2044567650 @default.
• W3104789637 cites W2045151350 @default.
• W3104789637 cites W2045557804 @default.
• W3104789637 cites W2054670281 @default.
• W3104789637 cites W2057831874 @default.
• W3104789637 cites W2057956576 @default.
• W3104789637 cites W2058041197 @default.
• W3104789637 cites W2059289107 @default.
• W3104789637 cites W2063618473 @default.
• W3104789637 cites W2063889028 @default.
• W3104789637 cites W2072486115 @default.
• W3104789637 cites W2088198801 @default.
• W3104789637 cites W2088512874 @default.
• W3104789637 cites W2088775719 @default.
• W3104789637 cites W2089439093 @default.
• W3104789637 cites W2093445888 @default.
• W3104789637 cites W2113506768 @default.
• W3104789637 cites W2116699009 @default.
• W3104789637 cites W2122250145 @default.
• W3104789637 cites W2128228409 @default.
• W3104789637 cites W2164386554 @default.
• W3104789637 cites W2212415466 @default.
• W3104789637 cites W2283223281 @default.
• W3104789637 cites W2301085974 @default.
• W3104789637 cites W2310435753 @default.
• W3104789637 cites W2313374373 @default.
• W3104789637 cites W2317513375 @default.
• W3104789637 cites W2318481604 @default.
• W3104789637 cites W2319226441 @default.
• W3104789637 cites W2320271627 @default.
• W3104789637 cites W2324862184 @default.
• W3104789637 cites W2325416032 @default.
• W3104789637 cites W2325708389 @default.
• W3104789637 cites W2331259322 @default.
• W3104789637 cites W2335345426 @default.
• W3104789637 cites W2411569176 @default.
• W3104789637 cites W2412921904 @default.
• W3104789637 cites W2460174040 @default.
• W3104789637 cites W2466974229 @default.
• W3104789637 cites W2468296212 @default.
• W3104789637 cites W2476396244 @default.
• W3104789637 cites W2479153560 @default.
• W3104789637 cites W2518139963 @default.
• W3104789637 cites W2519546456 @default.
• W3104789637 cites W2527959286 @default.
• W3104789637 cites W2533622506 @default.
• W3104789637 cites W2560207178 @default.
• W3104789637 cites W2564049585 @default.
• W3104789637 cites W2592140321 @default.
• W3104789637 cites W2617171480 @default.
• W3104789637 cites W2951540435 @default.
• W3104789637 cites W3102549934 @default.
• W3104789637 cites W4235697169 @default.
• W3104789637 doi "https://doi.org/10.1063/1.4995003" @default.
• W3104789637 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/29246057" @default.
• W3104789637 hasPublicationYear "2017" @default.
• W3104789637 type Work @default.
• W3104789637 sameAs 3104789637 @default.
• W3104789637 citedByCount "20" @default.
• W3104789637 countsByYear W31047896372018 @default.
• W3104789637 countsByYear W31047896372019 @default.
• W3104789637 countsByYear W31047896372020 @default.
• W3104789637 countsByYear W31047896372021 @default.

• next