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- W3105253148 abstract "It is demonstrated that strong laser pulses can introduce torsional motion in the axially chiral molecule 3,5-diflouro-3',5'-dibromo-biphenyl (DFDBrBPh). A nanosecond laser pulse spatially aligns the stereogenic carbon-carbon (C-C) bond axis allowing a perpendicularly polarized, intense femtosecond pulse to initiate torsional motion accompanied by a rotation about the fixed axis. We monitor the induced motion by femtosecond time-resolved Coulomb explosion imaging. Our theoretical analysis corroborates the experimental findings and on the basis of these results we discuss future applications of laser induced torsion, viz., time-resolved studies of de-racemization and laser controlled molecular junctions based on molecules with torsion." @default.
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- W3105253148 date "2009-06-21" @default.
- W3105253148 modified "2023-10-16" @default.
- W3105253148 title "A combined experimental and theoretical study on realizing and using laser controlled torsion of molecules" @default.
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- W3105253148 doi "https://doi.org/10.1063/1.3149789" @default.
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